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Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones
Liu, Tingting1,2; Chai, Huining1,2; Wang, Liandi1; Yu, Zhengkun1,3
Source PublicationORGANOMETALLICS
2017-08-14
DOI10.1021/acs.organomet.7b00356
Volume36Issue:15Pages:2914-2921
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordASYMMETRIC TRANSFER HYDROGENATION ; PYRAZOLYL-IMIDAZOLYL LIGAND ; HETEROMETALLIC COMPLEXES ; METAL-COMPLEXES ; NNN LIGAND ; BEARING ; OXIDATION ; OXYGEN ; WATER ; COOPERATIVITY
AbstractDinuclear ruthenium(II)-NNN complexes were efficiently assembled by means of coordinatively unsaturated 16-electron mononuclear ruthenium(II)-pyrazolyl-imidazolyl-pyridine complex and 4,4'-linked bipyridine ligands. The diruthenium(II)-NNN complex assembled through 4,4'-(CH2)(3)-bipyridine exhibited exceptionally high catalytic activity for the transfer hydrogenation (TH) of ketones in refluxing 2-propanol and reached TOF values up to 1.4 x 10(7) h(-1), demonstrating a remarkable cooperative effect from the ruthenium(II)-NNN functionalities.
Language英语
WOS IDWOS:000407869100025
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/149821
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Liu, Tingting,Chai, Huining,Wang, Liandi,et al. Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones[J]. ORGANOMETALLICS,2017,36(15):2914-2921.
APA Liu, Tingting,Chai, Huining,Wang, Liandi,&Yu, Zhengkun.(2017).Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones.ORGANOMETALLICS,36(15),2914-2921.
MLA Liu, Tingting,et al."Exceptionally Active Assembled Dinuclear Ruthenium(II)-NNN Complex Catalysts for Transfer Hydrogenation of Ketones".ORGANOMETALLICS 36.15(2017):2914-2921.
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