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题名: Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization
作者: Zhang, Yongliang1;  Chi, Yue1;  Wei, Junnian1;  Yang, Qi1;  Yang, Zhenqiang2;  Chen, Hui2;  Yang, Ruina2;  Zhang, Wen-Xiong1;  Xi, Zhenfeng1, 2
刊名: ORGANOMETALLICS
发表日期: 2017-08-14
DOI: 10.1021/acs.organomet.7b00447
卷: 36, 期:15, 页:2982-2986
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Aromatic 1,1,2,2-tetralithiodigalloles 5 with a Ga-Ga bond were realized. Reaction of 1,4-dilithio-1,3-butadienes 6 with 0.5 equiv of GaCl3 afforded lithium spirogallane ate complexes 7 in excellent isolated yields. Reduction of the above ate complexes 7 with an excess amount of lithium generated the 1,1,2,2-tetralithiodigalloles 5 in moderate isolated yields. The structures of compounds 5 and 7 were both determined by single-crystal X-ray structural analysis. The 1,1,2,2-tetralithiodigalloles 5 contained two aromatic dilithiogalloles connected by a Ga-Ga bond. The aromaticity of 5 was confirmed by both experimental measurements (X-ray structural analysis, NMR spectroscopy) and theoretical analysis (ISE, NICS).
关键词[WOS]: IN-IN BONDS ;  MOLECULAR-STRUCTURE ;  GALLIUM-GALLIUM ;  AL-AL ;  ORGANOELEMENT COMPOUNDS ;  STANNOLE DIANION ;  TRANSITION-METAL ;  CHEMISTRY ;  METALLABENZENES ;  COMPLEXES
语种: 英语
WOS记录号: WOS:000407869100034
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149848
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China
2.Henan Acad Sci, Henan Inst Chem Co Ltd, Zhengzhou 450002, Henan, Peoples R China

Recommended Citation:
Zhang, Yongliang,Chi, Yue,Wei, Junnian,et al. Aromatic Tetralithiodigalloles with a Ga-Ga Bond: Synthesis and Structural Characterization[J]. ORGANOMETALLICS,2017,36(15):2982-2986.
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