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Selective hydrogenation of acetylene in an ethylene-rich stream over silica supported Ag-Ni bimetallic catalysts
Pei, Guang Xian1,2; Liu, Xiao Yan1; Wang, Aiqin1; Su, Yang1; Li, Lin1; Zhang, Tao1
关键词Ni Ag Acetylene Selective Hydrogenation Excess Ethylene
刊名APPLIED CATALYSIS A-GENERAL
2017-09-05
DOI10.1016/j.apcata.2017.07.041
545页:90-96
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine
类目[WOS]Chemistry, Physical ; Environmental Sciences
研究领域[WOS]Chemistry ; Environmental Sciences & Ecology
关键词[WOS]PD CATALYSTS ; CHEMOSELECTIVE HYDROGENATION ; UNSATURATED-HYDROCARBONS ; ALKYNE HYDROGENATION ; PALLADIUM CATALYSTS ; CU/AL2O3 CATALYSTS ; NICKEL-CATALYSTS ; DIMETHYL OXALATE ; ALLOY CATALYSTS ; EXCESS ETHYLENE
英文摘要Semi-hydrogenation of acetylene in an ethylene-rich stream is an industrially important process. Recent work on the purification of ethylene mainly focuses on the modification of Pd catalysts; little attention has been paid to the development of alternative catalysts with low-cost metals. Herein, a series of Ag-Ni/SiO2 bimetallic catalysts, with varied Ni/Ag atomic ratios, were prepared by wetness co-impregnation method. Their activity for the selective hydrogenation of acetylene in an ethylene-rich stream was evaluated, which showed that the introduction of Ag decreased the formation of both ethane and methane, thus increased the ethylene selectivity. The ethylene selectivity over the AgNi0.25/SiO2 catalyst was increased by > 600% when compared with the corresponding monometallic Ni-0.25/SiO2 as well as the simple physical mixture of the monometallic Ag/SiO2 and Ni-0.25/SiO2 catalysts. As was verified by a combination of the X-ray diffraction, high angular annular dark field scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy under scanning transmission electron microscopy results, decreased Ni content induced the sintering of the bimetallic nanoparticles while with uniform dispersion. Temperature-programmed reduction results demonstrated that, compared with the corresponding monometallic catalysts, both the reduction of AgOx and NiOx were promoted in the Ag-Ni/SiO2 bimetallic catalysts. In-situ Fourier-transform infrared spectroscopy results also illustrated obvious interaction between Ag and Ni. The contact between Ag and Ni may account for the enhanced ethylene selectivity.
语种英语
WOS记录号WOS:000410252900011
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/149867
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, IChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Pei, Guang Xian,Liu, Xiao Yan,Wang, Aiqin,et al. Selective hydrogenation of acetylene in an ethylene-rich stream over silica supported Ag-Ni bimetallic catalysts[J]. APPLIED CATALYSIS A-GENERAL,2017,545:90-96.
APA Pei, Guang Xian,Liu, Xiao Yan,Wang, Aiqin,Su, Yang,Li, Lin,&Zhang, Tao.(2017).Selective hydrogenation of acetylene in an ethylene-rich stream over silica supported Ag-Ni bimetallic catalysts.APPLIED CATALYSIS A-GENERAL,545,90-96.
MLA Pei, Guang Xian,et al."Selective hydrogenation of acetylene in an ethylene-rich stream over silica supported Ag-Ni bimetallic catalysts".APPLIED CATALYSIS A-GENERAL 545(2017):90-96.
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