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题名: Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes
作者: Kong, Lingheng1, 2;  Liu, Bingxian3;  Zhou, Xukai1, 2;  Wang, Fen1;  Li, Xingwei1
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2017-09-21
DOI: 10.1039/c7cc06048c
卷: 53, 期:74, 页:10326-10329
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Rhodium(III)-catalyzed mild benzylic alpha-fluoroalkenylation of 8-methyl-quinolines with gem-difluorostyrenes has been developed. This reaction occurred via C-H activation and C-F cleavage and is applicable to a wide range of substrates, leading to the synthesis of Z-alkenyl fluorides under mild and redox-neutral conditions with high regio- and stereoselectivity.
关键词[WOS]: C-H BONDS ;  C(SP(3))-H BONDS ;  INTERMOLECULAR AMIDATION ;  4+1 ANNULATION ;  ACTIVATION ;  CATALYSIS ;  8-METHYLQUINOLINES ;  FUNCTIONALIZATION ;  ARYLATION ;  ALKYLATION
语种: 英语
WOS记录号: WOS:000410942000020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149922
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China

Recommended Citation:
Kong, Lingheng,Liu, Bingxian,Zhou, Xukai,et al. Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes[J]. CHEMICAL COMMUNICATIONS,2017,53(74):10326-10329.
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