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Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes
Kong, Lingheng1,2; Liu, Bingxian3; Zhou, Xukai1,2; Wang, Fen1; Li, Xingwei1
刊名CHEMICAL COMMUNICATIONS
2017-09-21
DOI10.1039/c7cc06048c
53期:74页:10326-10329
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]C-H BONDS ; C(SP(3))-H BONDS ; INTERMOLECULAR AMIDATION ; 4+1 ANNULATION ; ACTIVATION ; CATALYSIS ; 8-METHYLQUINOLINES ; FUNCTIONALIZATION ; ARYLATION ; ALKYLATION
英文摘要Rhodium(III)-catalyzed mild benzylic alpha-fluoroalkenylation of 8-methyl-quinolines with gem-difluorostyrenes has been developed. This reaction occurred via C-H activation and C-F cleavage and is applicable to a wide range of substrates, leading to the synthesis of Z-alkenyl fluorides under mild and redox-neutral conditions with high regio- and stereoselectivity.
语种英语
WOS记录号WOS:000410942000020
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/149922
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
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GB/T 7714
Kong, Lingheng,Liu, Bingxian,Zhou, Xukai,et al. Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes[J]. CHEMICAL COMMUNICATIONS,2017,53(74):10326-10329.
APA Kong, Lingheng,Liu, Bingxian,Zhou, Xukai,Wang, Fen,&Li, Xingwei.(2017).Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes.CHEMICAL COMMUNICATIONS,53(74),10326-10329.
MLA Kong, Lingheng,et al."Rhodium(III)-catalyzed regio- and stereoselective benzylic alpha-fluoroalkenylation with gem-difluorostyrenes".CHEMICAL COMMUNICATIONS 53.74(2017):10326-10329.
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