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题名: Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent
作者: Shi, Song1;  Liu, Meng1, 2;  Zhao, Li1, 2;  Wang, Min1;  Chen, Chen1;  Gao, Jin1;  Xu, Jie1
关键词: alcohol ;  cobalt ;  hydrocarbon solvent ;  hydrophobic ;  oxidation
刊名: CHEMISTRY-AN ASIAN JOURNAL
发表日期: 2017-09-19
DOI: 10.1002/asia.201700717
卷: 12, 期:18, 页:2404-2409
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A hydrophobic cobalt catalyst was synthesized and proved to be effective in alcohol oxidation under the assistance of hydrocarbon solvent with oxygen as the terminal oxidant. A series of catalysts with different water contact angles was applied to investigate the hydrophobic effect. Further insight into the reaction process was gained by reaction kinetics, isotopic effect, etc. It showed that the hydrocarbon solvent participated in the alcohol oxidation, and with the aid of the in situ generated free radicals, the -C-H bond was smoothly activated and the alcohol was converted to carbonyl compounds. The hydrophobic effect promoted the alcohol oxidation by affecting the solvent oxidation.
关键词[WOS]: SELECTIVE AEROBIC OXIDATION ;  BASE-FREE CONDITIONS ;  OXIDE NANOPARTICLES ;  ALIPHATIC-ALCOHOLS ;  BENZYLIC ALCOHOLS ;  DEHYDROGENATION ;  WETTABILITY ;  CHEMISTRY ;  EFFICIENT ;  COMPLEXES
语种: 英语
WOS记录号: WOS:000411081300016
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149927
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Shi, Song,Liu, Meng,Zhao, Li,et al. Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(18):2404-2409.
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