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Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent
Shi, Song1; Liu, Meng1,2; Zhao, Li1,2; Wang, Min1; Chen, Chen1; Gao, Jin1; Xu, Jie1
关键词Alcohol Cobalt Hydrocarbon Solvent Hydrophobic Oxidation
刊名CHEMISTRY-AN ASIAN JOURNAL
2017-09-19
DOI10.1002/asia.201700717
12期:18页:2404-2409
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]SELECTIVE AEROBIC OXIDATION ; BASE-FREE CONDITIONS ; OXIDE NANOPARTICLES ; ALIPHATIC-ALCOHOLS ; BENZYLIC ALCOHOLS ; DEHYDROGENATION ; WETTABILITY ; CHEMISTRY ; EFFICIENT ; COMPLEXES
英文摘要A hydrophobic cobalt catalyst was synthesized and proved to be effective in alcohol oxidation under the assistance of hydrocarbon solvent with oxygen as the terminal oxidant. A series of catalysts with different water contact angles was applied to investigate the hydrophobic effect. Further insight into the reaction process was gained by reaction kinetics, isotopic effect, etc. It showed that the hydrocarbon solvent participated in the alcohol oxidation, and with the aid of the in situ generated free radicals, the -C-H bond was smoothly activated and the alcohol was converted to carbonyl compounds. The hydrophobic effect promoted the alcohol oxidation by affecting the solvent oxidation.
语种英语
WOS记录号WOS:000411081300016
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/149927
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Shi, Song,Liu, Meng,Zhao, Li,et al. Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(18):2404-2409.
APA Shi, Song.,Liu, Meng.,Zhao, Li.,Wang, Min.,Chen, Chen.,...&Xu, Jie.(2017).Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent.CHEMISTRY-AN ASIAN JOURNAL,12(18),2404-2409.
MLA Shi, Song,et al."Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent".CHEMISTRY-AN ASIAN JOURNAL 12.18(2017):2404-2409.
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