DICP OpenIR
One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone
Song, Lei1,2; Zheng, Mingyuan2; Pang, Jifeng2; Sebastian, Joby2; Wang, Wentao2; Qu, Minjie1; Zhao, Jian1; Wang, Xinhong1; Zhang, Tao2
Source PublicationGREEN CHEMISTRY
2017-08-07
DOI10.1039/c7gc00578d
Volume19Issue:15Pages:3515-3519
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordREDUCTIVE AMINATION ; PRIMARY AMINES ; ETHYLENE-GLYCOL ; CATALYSTS ; ACID ; 2-METHYLPYRAZINE ; CONVERSION ; OXIDATION ; PYRAZINE ; AMMONIA
AbstractAn efficient and green method for the synthesis of 2-hydroxymethyl-5-methylpyrazine was achieved from biomass derived 1,3-dihydroxyacetone and diammonium phosphate via a one-pot reaction. The product yield was as high as 72% under optimized conditions of pH = 8.0-9.1 at 90 degrees C for 1 hour in a dioxane and water mixture as a solvent. A possible reaction mechanism was proposed according to the reaction kinetics, NMR and in situ ATR-IR characterization studies.
Language英语
WOS IDWOS:000406615800005
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/149951
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Polytech Univ, Mat Sci & Engn, Dalian 116034, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Song, Lei,Zheng, Mingyuan,Pang, Jifeng,et al. One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone[J]. GREEN CHEMISTRY,2017,19(15):3515-3519.
APA Song, Lei.,Zheng, Mingyuan.,Pang, Jifeng.,Sebastian, Joby.,Wang, Wentao.,...&Zhang, Tao.(2017).One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone.GREEN CHEMISTRY,19(15),3515-3519.
MLA Song, Lei,et al."One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone".GREEN CHEMISTRY 19.15(2017):3515-3519.
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