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题名: Thiophene-Alkyne-Based CMPs as Highly Selective Regulators for Oxidative Heck Reaction
作者: Li, Ren-Hao1, 2;  Ding, Zong-Cang1, 2;  Li, Cun-Yao3;  Chen, Jun-Jia1, 2;  Zhou, Yun-Bing1, 2;  An, Xiao-Ming1, 2;  Ding, Yun-Jie3;  Zhan, Zhuang-Ping1, 2
刊名: ORGANIC LETTERS
发表日期: 2017-09-01
DOI: 10.1021/acs.orglett.7b01858
卷: 19, 期:17, 页:4432-4435
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Thiophenes containing an adjacent C C group as ligands for Pd-II-promoted organic reactions are reported for the first time. These ligands were utilized as catalytic sites and integrated into the skeleton of conjugated microporous polymers. By employing these CMP materials as selective regulators, oxidative Heck reactions between arylboronic esters and electronically unbiased alkenes provide highly selective linear products.
关键词[WOS]: CONJUGATED MICROPOROUS POLYMER ;  ALIPHATIC OLEFINS ;  ARYLBORONIC ACIDS ;  ARYL CHLORIDES ;  CATALYST ;  HALIDES ;  ARYLATION ;  EPOXIDES ;  LIGAND ;  OXYGEN
语种: 英语
WOS记录号: WOS:000409566400006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149970
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China
2.Xiamen Univ, Coll Chem & Chem Engn, Key Lab Chem Biol Fujian Prov, Xiamen 361005, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

Recommended Citation:
Li, Ren-Hao,Ding, Zong-Cang,Li, Cun-Yao,et al. Thiophene-Alkyne-Based CMPs as Highly Selective Regulators for Oxidative Heck Reaction[J]. ORGANIC LETTERS,2017,19(17):4432-4435.
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