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Silver-catalyzed cyclization of nitrones with 2-azetine: a radical approach to 2,3-disubstituted quinolines
Yan, Hao1,2; Li, Xincheng1; Wang, Chunxiang1; Wan, Boshun1
刊名ORGANIC CHEMISTRY FRONTIERS
2017-09-01
DOI10.1039/c7qo00405b
4期:9页:1833-1838
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]C BOND-CLEAVAGE ; 2+2+2 CYCLOADDITION ; POVAROV REACTION ; 2,4-DIARYLQUINOLINE DERIVATIVES ; POLYSUBSTITUTED QUINOLINES ; ROOM-TEMPERATURE ; H ACTIVATION ; IONIC LIQUID ; EASY ACCESS ; ALKYNES
英文摘要A silver-catalyzed intermolecular tandem cyclization of nitrones with 2-azetine was developed for the synthesis of 2,3-disubstituted quinolines under mild conditions with good yields. This approach features a C-N bond cleavage of 2-azetine and an N-O bond cleavage of nitrones via a radical pathway. The results of this study provide a new reaction pattern for nitrones and may find applications in the synthesis of other heterocycles.
语种英语
WOS记录号WOS:000408263400022
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/149976
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Yan, Hao,Li, Xincheng,Wang, Chunxiang,et al. Silver-catalyzed cyclization of nitrones with 2-azetine: a radical approach to 2,3-disubstituted quinolines[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(9):1833-1838.
APA Yan, Hao,Li, Xincheng,Wang, Chunxiang,&Wan, Boshun.(2017).Silver-catalyzed cyclization of nitrones with 2-azetine: a radical approach to 2,3-disubstituted quinolines.ORGANIC CHEMISTRY FRONTIERS,4(9),1833-1838.
MLA Yan, Hao,et al."Silver-catalyzed cyclization of nitrones with 2-azetine: a radical approach to 2,3-disubstituted quinolines".ORGANIC CHEMISTRY FRONTIERS 4.9(2017):1833-1838.
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