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题名: Rhodium(III)-catalyzed selective access to isoindolinones via formal [4+1] annulation of arylamides and propargyl alcohols
作者: Xu, Youwei1, 2;  Wang, Fen1;  Yu, Songjie1;  Li, Xingwei1
关键词: Rhodium ;  C-H activation ;  [4+1] annulation ;  Propargyl alcohol ;  Isoindolinones
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2017-08-01
DOI: 10.1016/S1872-2067(17)62881-X
卷: 38, 期:8, 页:1390-1398
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A mild and efficient oxidative synthesis of isoindolinones has been realized by Rh(III)-catalyzed C-H activation of benzamides and [4 + 1] coupling with propargyl alcohols. This coupling system proceeds with broad substrate scope and mild conditions and provides a new approach to access the useful skeleton of gamma-lactams with a stereogenic center. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: C-H ACTIVATION ;  BOND ACTIVATION ;  OXIDATIVE ANNULATION ;  POLYHETEROAROMATIC COMPOUNDS ;  FACILE SYNTHESIS ;  GAMMA-LACTAMS ;  ALKYNES ;  FUNCTIONALIZATIONS ;  INHIBITORS ;  BENZAMIDES
语种: 英语
WOS记录号: WOS:000408600200011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/149996
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Xu, Youwei,Wang, Fen,Yu, Songjie,et al. Rhodium(III)-catalyzed selective access to isoindolinones via formal [4+1] annulation of arylamides and propargyl alcohols[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(8):1390-1398.
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