DICP OpenIR
Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent
Shi, Song1; Liu, Meng1,2; Zhao, Li1,2; Wang, Min1; Chen, Chen1; Gao, Jin1; Xu, Jie1
KeywordAlcohol Cobalt Hydrocarbon Solvent Hydrophobic Oxidation
Source PublicationCHEMISTRY-AN ASIAN JOURNAL
2017-09-19
DOI10.1002/asia.201700717
Volume12Issue:18Pages:2404-2409
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordSELECTIVE AEROBIC OXIDATION ; BASE-FREE CONDITIONS ; OXIDE NANOPARTICLES ; ALIPHATIC-ALCOHOLS ; BENZYLIC ALCOHOLS ; DEHYDROGENATION ; WETTABILITY ; CHEMISTRY ; EFFICIENT ; COMPLEXES
AbstractA hydrophobic cobalt catalyst was synthesized and proved to be effective in alcohol oxidation under the assistance of hydrocarbon solvent with oxygen as the terminal oxidant. A series of catalysts with different water contact angles was applied to investigate the hydrophobic effect. Further insight into the reaction process was gained by reaction kinetics, isotopic effect, etc. It showed that the hydrocarbon solvent participated in the alcohol oxidation, and with the aid of the in situ generated free radicals, the -C-H bond was smoothly activated and the alcohol was converted to carbonyl compounds. The hydrophobic effect promoted the alcohol oxidation by affecting the solvent oxidation.
Language英语
WOS IDWOS:000411081300016
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150027
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Shi, Song,Liu, Meng,Zhao, Li,et al. Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(18):2404-2409.
APA Shi, Song.,Liu, Meng.,Zhao, Li.,Wang, Min.,Chen, Chen.,...&Xu, Jie.(2017).Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent.CHEMISTRY-AN ASIAN JOURNAL,12(18),2404-2409.
MLA Shi, Song,et al."Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent".CHEMISTRY-AN ASIAN JOURNAL 12.18(2017):2404-2409.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Shi, Song]'s Articles
[Liu, Meng]'s Articles
[Zhao, Li]'s Articles
Baidu academic
Similar articles in Baidu academic
[Shi, Song]'s Articles
[Liu, Meng]'s Articles
[Zhao, Li]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Shi, Song]'s Articles
[Liu, Meng]'s Articles
[Zhao, Li]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.