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题名: Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide
作者: Zheng, Xi1;  Ma, Jiping1;  Wang, Min1;  Shi, Song1;  Sun, Zhiqiang1;  Xu, Jie1
关键词: Cyclohexyl hydropemdde ;  Decomposition ;  Oxidation ;  Coupling reaction
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2017-11-01
DOI: 10.1016/j.catcom.2017.07.030
卷: 101, 页:77-80
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Coupling reaction of cyclohexyl hydroperoxide (CHHP) decomposition and cyclohexane oxidation in the process of catalytic decomposition of CHHP was identified via cyclopentane instead of cyclohexane used as solvent. A method was established to evaluate this coupling reaction. Based on this method, it can be accurately distinguished the product of cyclohexanol and cyclohexanone (K/A oil) derived from whether decomposition of CHHP or oxidation of cyclohexane. The established method is of great significance to the further study of the coupling reaction.
关键词[WOS]: AEROBIC OXIDATION ;  COMPLEXES ;  DEPEROXIDATION ;  PORPHYRINS ;  DINUCLEAR ;  LIGHT
语种: 英语
WOS记录号: WOS:000411552400017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/150094
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China

Recommended Citation:
Zheng, Xi,Ma, Jiping,Wang, Min,et al. Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide[J]. CATALYSIS COMMUNICATIONS,2017,101:77-80.
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