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Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters
Guo, Lisheng1,2; Sun, Jian1; Wei, Jian1,2; Wen, Zhiyong1,2; Xu, Hengyong1; Ge, Qingjie1
KeywordFischer-tropsch Synthesis Promoters Synergistic Effect Iron-based Catalysts Hydrocarbons
Source PublicationJOURNAL OF ENERGY CHEMISTRY
2017-07-01
DOI10.1016/j.jechem.2017.03.017
Volume26Issue:4Pages:632-638
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS Research AreaChemistry ; Energy & Fuels ; Engineering
WOS KeywordMANGANESE CATALYST ; NANOPARTICLES ; SELECTIVITY ; POTASSIUM
AbstractA sustainable strategy for Fischer-Tropsch iron catalysts is successfully achieved by embedding of synergistic promoters from a renewable resource, corncob. The iron-based catalysts, named as "corncob-driven" catalysts, are composed of iron species supported on carbon as primary active components and various minerals (K, Mg, Ca, and Si, etc.) as promoters. The corncob-driven catalysts are facilely synthesized by a one-pot hydrothermal treatment under mild conditions. The characterization results indicate that the formation of iron carbides from humboldtine is clearly enhanced and the morphology of catalyst particles tends to be more regular microspheres after adding corncob. It is observed that the optimized corncob-driven catalyst exhibits a higher conversion than without promoters' catalyst in Fischer-Tropsch synthesis (ca. 73% vs. ca. 49%). More importantly, a synergistic effect exists in multiple promoters from corncob that can enhance heavy hydrocarbons selectivity and lower CO2 selectivity, obviously different from the catalyst with promoters from chemicals. The proposed synthesis route of corncob-driven catalysts provides new strategies for the utilization of renewable resources and elimination of environmental pollutants from chemical promoters. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
Language英语
WOS IDWOS:000412776100006
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150107
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Guo, Lisheng,Sun, Jian,Wei, Jian,et al. Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(4):632-638.
APA Guo, Lisheng,Sun, Jian,Wei, Jian,Wen, Zhiyong,Xu, Hengyong,&Ge, Qingjie.(2017).Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters.JOURNAL OF ENERGY CHEMISTRY,26(4),632-638.
MLA Guo, Lisheng,et al."Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters".JOURNAL OF ENERGY CHEMISTRY 26.4(2017):632-638.
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