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Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols
Wang, Qingfu1,2; Chai, Huining1,2; Yu, Zhengkun1,3
刊名ORGANOMETALLICS
2017-09-25
DOI10.1021/acs.organomet.7b00587
36期:18页:3638-3644
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC TRANSFER HYDROGENATION ; CHIRAL IRIDIUM CATALYSTS ; IRON PINCER COMPLEX ; SELECTIVE HYDROGENATION ; IMIDAZOLYL LIGAND ; N-HETEROCYCLES ; CARBONYL-COMPOUNDS ; AMINO-ALCOHOLS ; NNN LIGAND ; ESTERS
英文摘要Dimeric pincer-type ruthenium(II)-NNN complexes bearing an unsymmetrical pyrazolyl-pyridylamino-pyridine ligand were prepared and characterized by NMR, elemental analysis, and X-ray single crystal structural determination. These complexes exhibited very high catalytic activity for both transfer hydrogenation of ketones and acceptorless dehydrogenation of secondary alcohols, achieving TOF values up to 1.9 x 10(6) h(-1) in the transfer hydrogenation of ketones. The high catalytic activity of the Ru(II) complex catalysts is attributed to the presence of the unprotected NH functionality in the ligand and hemilabile unsymmetrical coordination environment around the central metal atoms in the complex.
语种英语
WOS记录号WOS:000411914000024
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150108
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China
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GB/T 7714
Wang, Qingfu,Chai, Huining,Yu, Zhengkun. Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols[J]. ORGANOMETALLICS,2017,36(18):3638-3644.
APA Wang, Qingfu,Chai, Huining,&Yu, Zhengkun.(2017).Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols.ORGANOMETALLICS,36(18),3638-3644.
MLA Wang, Qingfu,et al."Dimeric Ruthenium(II)-NNN Complex Catalysts Bearing a Pyrazolyl-Pyridylamino-Pyridine Ligand for Transfer Hydrogenation of Ketones and Acceptorless Dehydrogenation of Alcohols".ORGANOMETALLICS 36.18(2017):3638-3644.
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