Non-aqueous lithium bromine battery of high energy density with carbon coated membrane

doi:10.1016/j.jechem.2017.04.013

DICP OpenIR

	Non-aqueous lithium bromine battery of high energy density with carbon coated membrane
	Xi, Xiaoli 1,2; Li, Xianfeng 1,3; Wang, Chenhui 1,2; Lai, Qinzhi 1; Cheng, Yuanhui 1,2; Xu, Pengcheng 1; Zhang, Huamin 1,3
关键词	Non-aqueous Battery Lithium Bromine Energy-storage
刊名	JOURNAL OF ENERGY CHEMISTRY
	2017-07-01
DOI	10.1016/j.jechem.2017.04.013
卷	26 期:4 页:639-646
收录类别	SCI
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
研究领域[WOS]	Chemistry ; Energy & Fuels ; Engineering
关键词[WOS]	REDOX FLOW BATTERY ; RESEARCH-AND-DEVELOPMENT ; STORAGE ; COMPOSITE ; ELECTROLYTES ; ABSORPTION ; PROGRESS ; SCIENCE ; IMPACT ; FUTURE
英文摘要	Flow batteries with high energy density and long cycle life have been pursued to advance the progress of energy storage and grid application. Non-aqueous batteries with wide voltage windows represent a promising technology without the limitation of water electrolysis, but they suffer from low electrolyte concentration and unsatisfactory battery performance. Here, a non-aqueous lithium bromine rechargeable battery is proposed, which is based on Br-2/Br and Li+/Li as active redox pairs, with fast redox kinetics and good stability. The Li/Br battery combines the advantages of high output voltage (similar to 3.1 V), electrolyte concentration (3.0 mol/L), maximum power density (29.1 mW/cm(2)) and practical energy density (232.6 Wh/kg). Additionally, the battery displays a columbic efficiency (CE) of 90.0%, a voltage efficiency (VE) of 88.0% and an energy efficiency (EE) of 80.0% at 1.0 mA/cm(2) after continuously running for more than 10 0 0 cycles, which is by far the longest cycle life reported for non-aqueous flow batteries. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
语种	英语
WOS记录号	WOS:000412776100007
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://cas-ir.dicp.ac.cn/handle/321008/150150
专题	中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Div Energy Storage, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Xi, Xiaoli,Li, Xianfeng,Wang, Chenhui,et al. Non-aqueous lithium bromine battery of high energy density with carbon coated membrane[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(4):639-646.
APA	Xi, Xiaoli.,Li, Xianfeng.,Wang, Chenhui.,Lai, Qinzhi.,Cheng, Yuanhui.,...&Zhang, Huamin.(2017).Non-aqueous lithium bromine battery of high energy density with carbon coated membrane.JOURNAL OF ENERGY CHEMISTRY,26(4),639-646.
MLA	Xi, Xiaoli,et al."Non-aqueous lithium bromine battery of high energy density with carbon coated membrane".JOURNAL OF ENERGY CHEMISTRY 26.4(2017):639-646.