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题名: Asymmetric Hydrogenation of Isoquinolines and Pyridines Using Hydrogen Halide Generated in Situ as Activator
作者: Chen, Mu-Wang1;  Ji, Yue1;  Wang, Jie1;  Chen, Qing-An1;  Shi, Lei1;  Zhou, Yong-Gui1, 2
刊名: ORGANIC LETTERS
发表日期: 2017-09-15
DOI: 10.1021/acs.orglett.7b02502
卷: 19, 期:18, 页:4988-4991
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: By employing halogenide trichloroisocyanuric acid as a traceless activation reagent, a general iridium-catalyzed asymmetric hydrogenation of isoquinolines and pyridines is developed with up to 99% ee. This method avoids tedious steps of installation and removal of the activating groups. The mechanism studies indicated that hydrogen halide generated in situ acted as an activator of isoquinolines and pyridines.
关键词[WOS]: IRIDIUM-CATALYZED HYDROGENATION ;  MULTIPLE STEREOGENIC CENTERS ;  HALOGEN-BOND FORMATION ;  ENANTIOSELECTIVE HYDROGENATION ;  DIPHOSPHINE LIGANDS ;  N-BROMOSUCCINIMIDE ;  SALTS ;  DERIVATIVES ;  COMPLEXES ;  BEARING
语种: 英语
WOS记录号: WOS:000411304300072
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/150166
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Chen, Mu-Wang,Ji, Yue,Wang, Jie,et al. Asymmetric Hydrogenation of Isoquinolines and Pyridines Using Hydrogen Halide Generated in Situ as Activator[J]. ORGANIC LETTERS,2017,19(18):4988-4991.
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