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Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide
Zheng, Xi; Ma, Jiping; Wang, Min; Shi, Song; Sun, Zhiqiang; Xu, Jie
KeywordCyclohexyl Hydropemdde Decomposition Oxidation Coupling Reaction
Source PublicationCATALYSIS COMMUNICATIONS
2017-11-01
DOI10.1016/j.catcom.2017.07.030
Volume101Pages:77-80
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordAEROBIC OXIDATION ; COMPLEXES ; DEPEROXIDATION ; PORPHYRINS ; DINUCLEAR ; LIGHT
AbstractCoupling reaction of cyclohexyl hydroperoxide (CHHP) decomposition and cyclohexane oxidation in the process of catalytic decomposition of CHHP was identified via cyclopentane instead of cyclohexane used as solvent. A method was established to evaluate this coupling reaction. Based on this method, it can be accurately distinguished the product of cyclohexanol and cyclohexanone (K/A oil) derived from whether decomposition of CHHP or oxidation of cyclohexane. The established method is of great significance to the further study of the coupling reaction.
Language英语
WOS IDWOS:000411552400017
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150194
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zheng, Xi,Ma, Jiping,Wang, Min,et al. Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide[J]. CATALYSIS COMMUNICATIONS,2017,101:77-80.
APA Zheng, Xi,Ma, Jiping,Wang, Min,Shi, Song,Sun, Zhiqiang,&Xu, Jie.(2017).Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide.CATALYSIS COMMUNICATIONS,101,77-80.
MLA Zheng, Xi,et al."Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide".CATALYSIS COMMUNICATIONS 101(2017):77-80.
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