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Cobalt(III)- and Rhodium(III)-Catalyzed C-H Amidation and Synthesis of 4-Quinolones: C-H Activation Assisted by Weakly Coordinating and Functionalizable Enaminone
Wang, Fen1,3; Jin, Liang1,2; Kong, Lingheng1; Li, Xingwei1
Source PublicationORGANIC LETTERS
2017-04-07
DOI10.1021/acs.orglett.7b00583
Volume19Issue:7Pages:1812-1815
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordN BOND FORMATION ; CARBON-NITROGEN BONDS ; ROOM-TEMPERATURE ; NATURAL-PRODUCTS ; AMIDO TRANSFER ; AMINATION ; ARENES ; AZIDES ; HETEROCYCLES ; REAGENTS
AbstractCobalt(III) and rhodiurn(III) catalysts exhibited complementary scope in C-H amidation of aryl enaminones. The amidation reactions proceeded with broad scope under the assistance of a weakly coordinating and bifunctional enaminone directing group. The electrophilicity of the enaminone group can be further utilized in subsequent hydrolysis-cyclization reactions to afford NH 4-quinolones in telescoping reactions.
Language英语
WOS IDWOS:000398985800081
Citation statistics
Cited Times:48[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150333
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Sch Chem & Chem Engn, Dalian 116023, Peoples R China
3.Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
Recommended Citation
GB/T 7714
Wang, Fen,Jin, Liang,Kong, Lingheng,et al. Cobalt(III)- and Rhodium(III)-Catalyzed C-H Amidation and Synthesis of 4-Quinolones: C-H Activation Assisted by Weakly Coordinating and Functionalizable Enaminone[J]. ORGANIC LETTERS,2017,19(7):1812-1815.
APA Wang, Fen,Jin, Liang,Kong, Lingheng,&Li, Xingwei.(2017).Cobalt(III)- and Rhodium(III)-Catalyzed C-H Amidation and Synthesis of 4-Quinolones: C-H Activation Assisted by Weakly Coordinating and Functionalizable Enaminone.ORGANIC LETTERS,19(7),1812-1815.
MLA Wang, Fen,et al."Cobalt(III)- and Rhodium(III)-Catalyzed C-H Amidation and Synthesis of 4-Quinolones: C-H Activation Assisted by Weakly Coordinating and Functionalizable Enaminone".ORGANIC LETTERS 19.7(2017):1812-1815.
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