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Ru-PPh3@porous organic polymer: efficient and stable catalyst for the trickle bed regioselective hydrogenation of cinnamaldehyde
Chen, Xingkun1,3; Zhu, Hejun1; Song, Xiangen1; Du, Hong1,3; Wang, Tao1,3; Zhao, Ziang1,3; Ding, Yunjie1,2
关键词Porous Organic Polymer Ruthenium Catalyst Cinnamaldehyde Hydrogenation Metal Support Interaction Continuous Trickle Bed
刊名REACTION KINETICS MECHANISMS AND CATALYSIS
2017-04-01
DOI10.1007/s11144-016-1130-6
120期:2页:637-649
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ; PHOSPHINE COMPLEX CATALYSTS ; BETA-UNSATURATED ALDEHYDE ; SELECTIVE HYDROGENATION ; RUTHENIUM COMPLEXES ; LIQUID-PHASE ; SULFONATED PHOSPHINES ; HOMOGENEOUS CATALYSIS ; SUPPORTED PLATINUM ; PD/SIO2 CATALYSTS
英文摘要Ru supported on the porous vinyl-functional triphenylphosphine organic polymer (Ru-PPh3@POP) as a heterogeneous catalyst for the selective hydrogenation of cinnamaldehyde (CAL) was synthesized. This catalyst, which combines the advantages of heterogeneous and homogeneous catalyst, showed much higher catalytic activity of continuous trickle bed hydrogenation of CAL than traditional inorganic material supported heterogeneous catalysts. The high efficiency of the Ru-PPh3@POP catalyst was attributed to the formation of the strong coordination bonds between the Ru species and the exposure phosphorus atoms on the surface of PPh3@POP support according to the results of EDS-mapping, P-31 NMR, XPS analysis and HRTEM. Importantly, Ru species maintained their nanoparticles without further aggregation during the long-term reaction, and thus the catalyst exhibited a high conversion of CAL of 55% and selectivity towards cinnamyl alcohol (COL) of 63% even over 312 h of time on stream of hydrogenation of CAL. The ICP results of the reaction solution revealed that there was no Ru leaching from the PPh3@POP support during the continuous reaction process. This excellent catalytic activity and stability make it very attractive. Our approaches provide a methodology to expand the heterogenized homogeneous catalysts widely spread in exploitation in fine chemical industries.
语种英语
WOS记录号WOS:000398722100016
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150337
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
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Chen, Xingkun,Zhu, Hejun,Song, Xiangen,et al. Ru-PPh3@porous organic polymer: efficient and stable catalyst for the trickle bed regioselective hydrogenation of cinnamaldehyde[J]. REACTION KINETICS MECHANISMS AND CATALYSIS,2017,120(2):637-649.
APA Chen, Xingkun.,Zhu, Hejun.,Song, Xiangen.,Du, Hong.,Wang, Tao.,...&Ding, Yunjie.(2017).Ru-PPh3@porous organic polymer: efficient and stable catalyst for the trickle bed regioselective hydrogenation of cinnamaldehyde.REACTION KINETICS MECHANISMS AND CATALYSIS,120(2),637-649.
MLA Chen, Xingkun,et al."Ru-PPh3@porous organic polymer: efficient and stable catalyst for the trickle bed regioselective hydrogenation of cinnamaldehyde".REACTION KINETICS MECHANISMS AND CATALYSIS 120.2(2017):637-649.
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