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Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization
Zhang, Yongliang1; Wei, Junnian1; Chi, Yue1; Zhang, Xuan1; Zhang, Wen-Xiong1; Xi, Zhenfeng1,2
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2017-04-12
DOI10.1021/jacs.7b02039
139期:14页:5039-5042
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]TRANSITION-METAL ; CHEMISTRY ; METALLABENZYNES ; DELOCALIZATION ; COMPLEXES ; MOLECULES ; LIGANDS ; STABILIZATION ; ACTIVATION ; DIANIONS
英文摘要Since the concept of aromaticity represents one of the most fundamental principles in chemistry, the search for unprecedented and exciting aromatic systems, therefore, continues to drive research in this area. Herein we report the synthesis and characterization of Spiro metalla-aromatics, in which the transition metal (Pd, Pt, or Rh) is the Spiro atom, that cross-conjugates two aromatic five-membered metallacycles. These Spiro metalla-aromatics tend to take square planar geometries, with the dihedral angle being influenced by the steric repulsion between the alpha-positioned substituents. Rationalized and classified via both experimental measurements (X-ray structural analysis, NMR spectroscopy, XPS, etc.) and theoretical analysis (DFT calculation, ISE, AICD, NICS, and CMOs), all these fundamental observations extend the concept of aromaticity and organometallic chemistry.
语种英语
WOS记录号WOS:000399353800015
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150340
专题中国科学院大连化学物理研究所
作者单位1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China
2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
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Zhang, Yongliang,Wei, Junnian,Chi, Yue,et al. Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(14):5039-5042.
APA Zhang, Yongliang,Wei, Junnian,Chi, Yue,Zhang, Xuan,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2017).Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(14),5039-5042.
MLA Zhang, Yongliang,et al."Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.14(2017):5039-5042.
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