DICP OpenIR
Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization
Zhang, Yongliang1; Wei, Junnian1; Chi, Yue1; Zhang, Xuan1; Zhang, Wen-Xiong1; Xi, Zhenfeng1,2
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2017-04-12
DOI10.1021/jacs.7b02039
Volume139Issue:14Pages:5039-5042
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordTRANSITION-METAL ; CHEMISTRY ; METALLABENZYNES ; DELOCALIZATION ; COMPLEXES ; MOLECULES ; LIGANDS ; STABILIZATION ; ACTIVATION ; DIANIONS
AbstractSince the concept of aromaticity represents one of the most fundamental principles in chemistry, the search for unprecedented and exciting aromatic systems, therefore, continues to drive research in this area. Herein we report the synthesis and characterization of Spiro metalla-aromatics, in which the transition metal (Pd, Pt, or Rh) is the Spiro atom, that cross-conjugates two aromatic five-membered metallacycles. These Spiro metalla-aromatics tend to take square planar geometries, with the dihedral angle being influenced by the steric repulsion between the alpha-positioned substituents. Rationalized and classified via both experimental measurements (X-ray structural analysis, NMR spectroscopy, XPS, etc.) and theoretical analysis (DFT calculation, ISE, AICD, NICS, and CMOs), all these fundamental observations extend the concept of aromaticity and organometallic chemistry.
Language英语
WOS IDWOS:000399353800015
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150340
Collection中国科学院大连化学物理研究所
Affiliation1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China
2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yongliang,Wei, Junnian,Chi, Yue,et al. Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(14):5039-5042.
APA Zhang, Yongliang,Wei, Junnian,Chi, Yue,Zhang, Xuan,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2017).Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(14),5039-5042.
MLA Zhang, Yongliang,et al."Spiro Metalla-aromatics of Pd, Pt, and Rh: Synthesis and Characterization".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.14(2017):5039-5042.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Yongliang]'s Articles
[Wei, Junnian]'s Articles
[Chi, Yue]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Yongliang]'s Articles
[Wei, Junnian]'s Articles
[Chi, Yue]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Yongliang]'s Articles
[Wei, Junnian]'s Articles
[Chi, Yue]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.