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Ruthenium-Catalyzed [3+2] Cycloaddition of 2H-Azirines with Alkynes: Access to Polysubstituted Pyrroles
Li, Tengfei1,2; Yan, Hao1,2; Li, Xincheng1; Wang, Chunxiang1; Wan, Boshun1
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2016-12-02
DOI10.1021/acs.joc.6b02322
Volume81Issue:23Pages:12031-12037
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS KeywordDIAZO OXIME ETHERS ; C BOND-CLEAVAGE ; STEREOSELECTIVE-SYNTHESIS ; MULTICOMPONENT REACTIONS ; SUBSTITUTED PYRROLES ; AEROBIC SYNTHESIS ; PYRIDINES ; DIYNES ; CYCLIZATION ; CHEMISTRY
AbstractA ruthenium-catalyzed intermolecular [3 + 2] cycloaddition of 2H-azirines and activated alkynes is reported, which provides polysubstituted pyrroles in moderate to good yields. This approach features a C-N bond cleavage of 2H-azirines by a ruthenium catalyst. The results of this study would provide a complementary method to synthesize polysubstituted pyrroles from the known 2H-azirine approaches and advance 2H-azirine chemistry.
Language英语
WOS IDWOS:000389396400055
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150422
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Tengfei,Yan, Hao,Li, Xincheng,et al. Ruthenium-Catalyzed [3+2] Cycloaddition of 2H-Azirines with Alkynes: Access to Polysubstituted Pyrroles[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(23):12031-12037.
APA Li, Tengfei,Yan, Hao,Li, Xincheng,Wang, Chunxiang,&Wan, Boshun.(2016).Ruthenium-Catalyzed [3+2] Cycloaddition of 2H-Azirines with Alkynes: Access to Polysubstituted Pyrroles.JOURNAL OF ORGANIC CHEMISTRY,81(23),12031-12037.
MLA Li, Tengfei,et al."Ruthenium-Catalyzed [3+2] Cycloaddition of 2H-Azirines with Alkynes: Access to Polysubstituted Pyrroles".JOURNAL OF ORGANIC CHEMISTRY 81.23(2016):12031-12037.
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