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Hierarchical mesoporous organic polymer with an intercalated metal complex for the efficient synthesis of cyclic carbonates from flue gas
Chen, Jian1,2; Li, He1; Zhong, Mingmei1,2; Yang, Qihua1
刊名GREEN CHEMISTRY
2016
DOI10.1039/c6gc02367c
18期:24页:6493-6500
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
关键词[WOS]HETEROGENEOUS CATALYST ; CO2 CAPTURE ; CONVERSION ; DIOXIDE ; FRAMEWORKS ; EPOXIDES ; PRESSURE ; STORAGE ; TRANSFORMATION ; CYCLOADDITION
英文摘要CO2 capture and utilization is one of the most attractive and challenging topics of the twenty-first century. The direct conversion of CO2 using flue gas as a feedstock is an energy saving process, but it has been rarely reported. Herein, we report an efficient CO2 cycloaddition reaction using diluted gas (20% CO2 and 80% N-2, simulating flue gas) as a feedstock, catalyzed by a 2,2'-bipyridine zinc(II) based hierarchical meso/microporous polymer, Bp-Zn@MA. Bp-Zn@MA, constructed via a template-free polycondensation reaction without using any catalyst, can efficiently catalyze the cycloaddition of propylene oxide with a TOF of up to 1580 h(-1) (100 degrees C) and 8041 h(-1) (150 degrees C), using diluted gas and pure CO2, respectively. This is among the best performing solid catalysts ever reported for the CO2 cycloaddition reaction. The high catalytic activity of the polymer, especially when diluted CO2 was employed, can be mainly attributed to its hierarchical meso/microporous structure, which contains mesopores for facilitating the diffusion of reactants and micropores for CO2 enrichment. The construction of this hierarchical structured porous material provides an efficient approach for realizing CO2 conversion using flue gas as a feedstock.
语种英语
WOS记录号WOS:000389341800010
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150424
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, iChEM, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Chen, Jian,Li, He,Zhong, Mingmei,et al. Hierarchical mesoporous organic polymer with an intercalated metal complex for the efficient synthesis of cyclic carbonates from flue gas[J]. GREEN CHEMISTRY,2016,18(24):6493-6500.
APA Chen, Jian,Li, He,Zhong, Mingmei,&Yang, Qihua.(2016).Hierarchical mesoporous organic polymer with an intercalated metal complex for the efficient synthesis of cyclic carbonates from flue gas.GREEN CHEMISTRY,18(24),6493-6500.
MLA Chen, Jian,et al."Hierarchical mesoporous organic polymer with an intercalated metal complex for the efficient synthesis of cyclic carbonates from flue gas".GREEN CHEMISTRY 18.24(2016):6493-6500.
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