DICP OpenIR
Scalable synthesis of secondary and tertiary amines by heterogeneous Pt-Sn/gamma-Al2O3 catalyzed N-alkylation of amines with alcohols
Wu, Kaikai; He, Wei; Sun, Chenglin; Yu, Zhengkun
关键词Alcohols Alkylation Amines Borrowing Hydrogen Pt-sn/gamma-al2o3
刊名TETRAHEDRON
2016-12-22
DOI10.1016/j.tet.2016.11.029
72期:51页:8516-8521
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
关键词[WOS]BORROWING HYDROGEN METHODOLOGY ; ONE-POT SYNTHESIS ; COUPLING REACTIONS ; PT-SN/AL2O3 CATALYSTS ; SUBSTITUTED AMINES ; ALUMINA SUPPORT ; C-N ; AMINATION ; AMMONIA ; EFFICIENT
英文摘要Synthesis of secondary and tertiary amines has been efficiently realized from the N-alkylation of amines with alcohols by means of heterogeneous bimetallic Pt-Sn/gamma-Al2O3 catalyst (0.5 wt % Pt, molar ratio Pt:Sn = 1:3) through a borrowing hydrogen strategy. The Pt-Sn/gamma-Al2O3 catalyst has exhibited very high catalytic activity towards a wide range of amines andalcohols, and can be conveniently recycled without Pt metal leaching. The present protocol was applied for the synthesis of N-phenylbenzylamine in 96% isolated yield from aniline and benzyl alcohol on a 2.1 kg scale of the substrates, demonstrating its potential applicability for higher-order amine synthesis. (C) 2016 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000389286200021
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150427
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Wu, Kaikai,He, Wei,Sun, Chenglin,et al. Scalable synthesis of secondary and tertiary amines by heterogeneous Pt-Sn/gamma-Al2O3 catalyzed N-alkylation of amines with alcohols[J]. TETRAHEDRON,2016,72(51):8516-8521.
APA Wu, Kaikai,He, Wei,Sun, Chenglin,&Yu, Zhengkun.(2016).Scalable synthesis of secondary and tertiary amines by heterogeneous Pt-Sn/gamma-Al2O3 catalyzed N-alkylation of amines with alcohols.TETRAHEDRON,72(51),8516-8521.
MLA Wu, Kaikai,et al."Scalable synthesis of secondary and tertiary amines by heterogeneous Pt-Sn/gamma-Al2O3 catalyzed N-alkylation of amines with alcohols".TETRAHEDRON 72.51(2016):8516-8521.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wu, Kaikai]的文章
[He, Wei]的文章
[Sun, Chenglin]的文章
百度学术
百度学术中相似的文章
[Wu, Kaikai]的文章
[He, Wei]的文章
[Sun, Chenglin]的文章
必应学术
必应学术中相似的文章
[Wu, Kaikai]的文章
[He, Wei]的文章
[Sun, Chenglin]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。