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Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers
Liu, Zhongshan1,2; Ou, Junjie1; Wang, Hongwei1; You, Xin1,2; Ye, Mingliang1
KeywordHydrazide Amide Porous Organic Polymer Hollow Structure Enrichment Of Glycopeptide
Source PublicationACS Applied Materials & Interfaces
2016-11-23
DOI10.1021/acsami.6b11572
Volume8Issue:46Pages:32060-32067
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS KeywordSOLID-PHASE EXTRACTION ; INTERACTION LIQUID-CHROMATOGRAPHY ; INTRINSIC MICROPOROSITY PIMS ; MAGNETIC NANOPARTICLES ; STATIONARY-PHASE ; HYDROGEN STORAGE ; ROOM-TEMPERATURE ; CO2 CAPTURE ; FRAMEWORKS ; GLYCOPEPTIDES
AbstractFour kinds of either hydrazide-linked or amide-linked polymers were facilely synthesized by using hydrazine, tetrakis(4-aminophenyl)methane (TAPM), terephthaloyl chloride (TPC), and trimesoyl chloride (TMC) as building blocks. The morphology, porosity, composition, and surface property of polymers were characterized by scanning electron microscopy, transmission electron microscopy, nitrogen adsorption-desorption-measurement, C-13/CP-MAS NMR, X-ray photoelectron spectroscopy, etc. The results indicated that building blocks had important effects on morphology and porosity. Poly(TMC-TAPM) synthesized with TMC and TAPM showed the highest surface area of 241.9 m(2) g(-1). In addition, note that a hollow structure with similar to 20 run wall thickness was formed in poly(TMC hydrazine) prepared with TMC and hydrazine. Further study indicated that both carboxyl groups (-COOH) and hydrazide groups (-CONH-NH2) existed on the surface of poly(TMC-hydrazine), besides the mainly hydrazide linkage (-CONH-NHOC-). Taking advantages of good hydrophilicity and special functional groups on the surface, we finally adopted poly(TMC hydrazine) to enrich glycopeptides from tryptic digest via both hydrophilic interaction chromatography method with identification of 369 unique N-glycosylation sites and hydrazide chemistry method with identification of 88 unique N-glycosylation sites, respectively.
Language英语
WOS IDWOS:000388913900068
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150437
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, Zhongshan,Ou, Junjie,Wang, Hongwei,et al. Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers[J]. ACS Applied Materials & Interfaces,2016,8(46):32060-32067.
APA Liu, Zhongshan,Ou, Junjie,Wang, Hongwei,You, Xin,&Ye, Mingliang.(2016).Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers.ACS Applied Materials & Interfaces,8(46),32060-32067.
MLA Liu, Zhongshan,et al."Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers".ACS Applied Materials & Interfaces 8.46(2016):32060-32067.
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