DICP OpenIR
Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion
Liu, Zhen1; Xia, Ying1; Feng, Sheng1; Zhang, Yan1; Wang, Jianbo1,2
刊名ORGANIC CHEMISTRY FRONTIERS
2016
DOI10.1039/c6qo00453a
3期:12页:1691-1698
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
关键词[WOS]ALPHA-DIAZOCARBONYL COMPOUNDS ; H BOND FUNCTIONALIZATION ; KETENE DIETHYL ACETAL ; C-C BOND ; METAL CARBENE ; ORGANIC-SYNTHESIS ; DIAZO-COMPOUNDS ; DIAZOESTERS ; CYCLOADDITIONS ; ARYLATION
英文摘要A Rh(I)-catalyzed cross-coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols has been successfully achieved. This reaction follows a reaction sequence which involves C-C bond cleavage, Rh(I) carbene formation, carbene migratory insertion and nucleophilic substitution to achieve the construction of C(sp(2))-C(sp) and C-O bonds. The products feature both enyne and ketene acetal moieties, which have been widely used as building blocks in organic synthesis and polymer science.
语种英语
WOS记录号WOS:000388675600013
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150438
专题中国科学院大连化学物理研究所
作者单位1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Liu, Zhen,Xia, Ying,Feng, Sheng,et al. Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(12):1691-1698.
APA Liu, Zhen,Xia, Ying,Feng, Sheng,Zhang, Yan,&Wang, Jianbo.(2016).Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion.ORGANIC CHEMISTRY FRONTIERS,3(12),1691-1698.
MLA Liu, Zhen,et al."Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion".ORGANIC CHEMISTRY FRONTIERS 3.12(2016):1691-1698.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Liu, Zhen]的文章
[Xia, Ying]的文章
[Feng, Sheng]的文章
百度学术
百度学术中相似的文章
[Liu, Zhen]的文章
[Xia, Ying]的文章
[Feng, Sheng]的文章
必应学术
必应学术中相似的文章
[Liu, Zhen]的文章
[Xia, Ying]的文章
[Feng, Sheng]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。