DICP OpenIR
Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion
Liu, Zhen1; Xia, Ying1; Feng, Sheng1; Zhang, Yan1; Wang, Jianbo1,2
Source PublicationORGANIC CHEMISTRY FRONTIERS
2016
DOI10.1039/c6qo00453a
Volume3Issue:12Pages:1691-1698
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS KeywordALPHA-DIAZOCARBONYL COMPOUNDS ; H BOND FUNCTIONALIZATION ; KETENE DIETHYL ACETAL ; C-C BOND ; METAL CARBENE ; ORGANIC-SYNTHESIS ; DIAZO-COMPOUNDS ; DIAZOESTERS ; CYCLOADDITIONS ; ARYLATION
AbstractA Rh(I)-catalyzed cross-coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols has been successfully achieved. This reaction follows a reaction sequence which involves C-C bond cleavage, Rh(I) carbene formation, carbene migratory insertion and nucleophilic substitution to achieve the construction of C(sp(2))-C(sp) and C-O bonds. The products feature both enyne and ketene acetal moieties, which have been widely used as building blocks in organic synthesis and polymer science.
Language英语
WOS IDWOS:000388675600013
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150438
Collection中国科学院大连化学物理研究所
Affiliation1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
Recommended Citation
GB/T 7714
Liu, Zhen,Xia, Ying,Feng, Sheng,et al. Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(12):1691-1698.
APA Liu, Zhen,Xia, Ying,Feng, Sheng,Zhang, Yan,&Wang, Jianbo.(2016).Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion.ORGANIC CHEMISTRY FRONTIERS,3(12),1691-1698.
MLA Liu, Zhen,et al."Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion".ORGANIC CHEMISTRY FRONTIERS 3.12(2016):1691-1698.
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