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题名: Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion
作者: Liu, Zhen1;  Xia, Ying1;  Feng, Sheng1;  Zhang, Yan1;  Wang, Jianbo1, 2
刊名: ORGANIC CHEMISTRY FRONTIERS
发表日期: 2016
DOI: 10.1039/c6qo00453a
卷: 3, 期:12, 页:1691-1698
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
英文摘要: A Rh(I)-catalyzed cross-coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols has been successfully achieved. This reaction follows a reaction sequence which involves C-C bond cleavage, Rh(I) carbene formation, carbene migratory insertion and nucleophilic substitution to achieve the construction of C(sp(2))-C(sp) and C-O bonds. The products feature both enyne and ketene acetal moieties, which have been widely used as building blocks in organic synthesis and polymer science.
关键词[WOS]: ALPHA-DIAZOCARBONYL COMPOUNDS ;  H BOND FUNCTIONALIZATION ;  KETENE DIETHYL ACETAL ;  C-C BOND ;  METAL CARBENE ;  ORGANIC-SYNTHESIS ;  DIAZO-COMPOUNDS ;  DIAZOESTERS ;  CYCLOADDITIONS ;  ARYLATION
语种: 英语
WOS记录号: WOS:000388675600013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/150438
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Liu, Zhen,Xia, Ying,Feng, Sheng,et al. Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(12):1691-1698.
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