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题名: Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission
作者: Wang, Fen1;  Yu, Songjie1;  Li, Xingwei1
刊名: CHEMICAL SOCIETY REVIEWS
发表日期: 2016
DOI: 10.1039/c6cs00371k
卷: 45, 期:23, 页:6462-6477
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
英文摘要: Organic transformations that involve direct functionalization of C-H bonds represent an attractive synthetic strategy that maximizes atom-and step-economy. With the generally high stability of C-H bonds, these processes have mostly required harsh reaction conditions, in combination with the necessity of activation of the C-H substrates and/or the coupling partners. As a class of activated coupling partners, strained or reactive rings exhibited high activity in the coupling with aryl and alkyl C-H bonds. Such a high reactivity of the rings allowed the facile construction of various new structural platforms via coupling with scission of the ring structures. The combination of C-H activation and scission of the rings allowed for applications of a broader scope of C-H bonds, including those less reactive alkyl ones. This synthetic diversity of these rings has been realized owing to the intrinsically different mechanisms of the interactions of transition metal catalysts and the strained/reactive rings.
关键词[WOS]: S-ARYL SULFOXIMINES ;  HETEROBICYCLIC ALKENES ;  BOND-CLEAVAGE ;  METHYLENECYCLOPROPANES ;  AMIDATION ;  ACTIVATION/CYCLOADDITION ;  HETEROCYCLES ;  DERIVATIVES ;  FUNCTIONALIZATION ;  PYRIDOTRIAZOLES
语种: 英语
WOS记录号: WOS:000389318100004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/150442
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Fen,Yu, Songjie,Li, Xingwei. Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission[J]. CHEMICAL SOCIETY REVIEWS,2016,45(23):6462-6477.
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