DICP OpenIR
Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission
Wang, Fen; Yu, Songjie; Li, Xingwei
Source PublicationCHEMICAL SOCIETY REVIEWS
2016
DOI10.1039/c6cs00371k
Volume45Issue:23Pages:6462-6477
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS KeywordS-ARYL SULFOXIMINES ; HETEROBICYCLIC ALKENES ; BOND-CLEAVAGE ; METHYLENECYCLOPROPANES ; AMIDATION ; ACTIVATION/CYCLOADDITION ; HETEROCYCLES ; DERIVATIVES ; FUNCTIONALIZATION ; PYRIDOTRIAZOLES
AbstractOrganic transformations that involve direct functionalization of C-H bonds represent an attractive synthetic strategy that maximizes atom-and step-economy. With the generally high stability of C-H bonds, these processes have mostly required harsh reaction conditions, in combination with the necessity of activation of the C-H substrates and/or the coupling partners. As a class of activated coupling partners, strained or reactive rings exhibited high activity in the coupling with aryl and alkyl C-H bonds. Such a high reactivity of the rings allowed the facile construction of various new structural platforms via coupling with scission of the ring structures. The combination of C-H activation and scission of the rings allowed for applications of a broader scope of C-H bonds, including those less reactive alkyl ones. This synthetic diversity of these rings has been realized owing to the intrinsically different mechanisms of the interactions of transition metal catalysts and the strained/reactive rings.
Language英语
WOS IDWOS:000389318100004
Citation statistics
Cited Times:108[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/150442
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Wang, Fen,Yu, Songjie,Li, Xingwei. Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission[J]. CHEMICAL SOCIETY REVIEWS,2016,45(23):6462-6477.
APA Wang, Fen,Yu, Songjie,&Li, Xingwei.(2016).Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission.CHEMICAL SOCIETY REVIEWS,45(23),6462-6477.
MLA Wang, Fen,et al."Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission".CHEMICAL SOCIETY REVIEWS 45.23(2016):6462-6477.
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