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Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission
Wang, Fen; Yu, Songjie; Li, Xingwei
刊名CHEMICAL SOCIETY REVIEWS
2016
DOI10.1039/c6cs00371k
45期:23页:6462-6477
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
关键词[WOS]S-ARYL SULFOXIMINES ; HETEROBICYCLIC ALKENES ; BOND-CLEAVAGE ; METHYLENECYCLOPROPANES ; AMIDATION ; ACTIVATION/CYCLOADDITION ; HETEROCYCLES ; DERIVATIVES ; FUNCTIONALIZATION ; PYRIDOTRIAZOLES
英文摘要Organic transformations that involve direct functionalization of C-H bonds represent an attractive synthetic strategy that maximizes atom-and step-economy. With the generally high stability of C-H bonds, these processes have mostly required harsh reaction conditions, in combination with the necessity of activation of the C-H substrates and/or the coupling partners. As a class of activated coupling partners, strained or reactive rings exhibited high activity in the coupling with aryl and alkyl C-H bonds. Such a high reactivity of the rings allowed the facile construction of various new structural platforms via coupling with scission of the ring structures. The combination of C-H activation and scission of the rings allowed for applications of a broader scope of C-H bonds, including those less reactive alkyl ones. This synthetic diversity of these rings has been realized owing to the intrinsically different mechanisms of the interactions of transition metal catalysts and the strained/reactive rings.
语种英语
WOS记录号WOS:000389318100004
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150442
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Wang, Fen,Yu, Songjie,Li, Xingwei. Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission[J]. CHEMICAL SOCIETY REVIEWS,2016,45(23):6462-6477.
APA Wang, Fen,Yu, Songjie,&Li, Xingwei.(2016).Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission.CHEMICAL SOCIETY REVIEWS,45(23),6462-6477.
MLA Wang, Fen,et al."Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C-H activation and ring scission".CHEMICAL SOCIETY REVIEWS 45.23(2016):6462-6477.
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