中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Enantiomeric Catalytic Formal Thiolation of 2,5-Dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles in an Oil/Water Biphasic System
作者: Chen, Ping1, 2;  Yang, Qin1;  Lu, Shengmei1;  Wang, Peng1;  Liu, Yan1;  Li, Can1
关键词: Asymmetric synthesis ;  Conjugate addition ;  Enantioselectivity ;  Nitrogen heterocycles ;  Organocatalysis
刊名: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2016-12-01
DOI: 10.1002/ejoc.201601180
期: 35, 页:5826-5830
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The asymmetric synthesis of 3-sec-substituted pyrrole derivatives through vinylogous imine intermediates generated in situ from 2,5-dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles with high activity and enantioselectivity (up to 98% ee) was examined. Employing a cinchona alkaloid based chiral bifunctional organocatalyst, the reaction of tritylthiol to sulfonylpyrroles delivered a series of highly enantioselective sulfur-containing 3-sec-substituted pyrroles.
关键词[WOS]: BETA-SUBSTITUTED TRYPTOPHANS ;  ASYMMETRIC MICHAEL ADDITION ;  DIELS-ALDER REACTIONS ;  GENERATED IN-SITU ;  ANTIMALARIAL ACTIVITY ;  ENANTIOSELECTIVE SYNTHESIS ;  CONJUGATE ADDITION ;  EMULSION DROPLETS ;  CYCLOPRODIGIOSIN HYDROCHLORIDE ;  ABSOLUTE-CONFIGURATION
语种: 英语
WOS记录号: WOS:000390780000008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/150509
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Chen, Ping,Yang, Qin,Lu, Shengmei,et al. Enantiomeric Catalytic Formal Thiolation of 2,5-Dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles in an Oil/Water Biphasic System[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2016(35):5826-5830.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Chen, Ping]'s Articles
 [Yang, Qin]'s Articles
 [Lu, Shengmei]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Chen, Ping]‘s Articles
 [Yang, Qin]‘s Articles
 [Lu, Shengmei]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace