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Enantiomeric Catalytic Formal Thiolation of 2,5-Dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles in an Oil/Water Biphasic System
Chen, Ping1,2; Yang, Qin1; Lu, Shengmei1; Wang, Peng1; Liu, Yan1; Li, Can1
关键词Asymmetric Synthesis Conjugate Addition Enantioselectivity Nitrogen Heterocycles Organocatalysis
刊名EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
2016-12-01
DOI10.1002/ejoc.201601180
35页:5826-5830
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]BETA-SUBSTITUTED TRYPTOPHANS ; ASYMMETRIC MICHAEL ADDITION ; DIELS-ALDER REACTIONS ; GENERATED IN-SITU ; ANTIMALARIAL ACTIVITY ; ENANTIOSELECTIVE SYNTHESIS ; CONJUGATE ADDITION ; EMULSION DROPLETS ; CYCLOPRODIGIOSIN HYDROCHLORIDE ; ABSOLUTE-CONFIGURATION
英文摘要The asymmetric synthesis of 3-sec-substituted pyrrole derivatives through vinylogous imine intermediates generated in situ from 2,5-dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles with high activity and enantioselectivity (up to 98% ee) was examined. Employing a cinchona alkaloid based chiral bifunctional organocatalyst, the reaction of tritylthiol to sulfonylpyrroles delivered a series of highly enantioselective sulfur-containing 3-sec-substituted pyrroles.
语种英语
WOS记录号WOS:000390780000008
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/150509
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Chen, Ping,Yang, Qin,Lu, Shengmei,et al. Enantiomeric Catalytic Formal Thiolation of 2,5-Dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles in an Oil/Water Biphasic System[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2016(35):5826-5830.
APA Chen, Ping,Yang, Qin,Lu, Shengmei,Wang, Peng,Liu, Yan,&Li, Can.(2016).Enantiomeric Catalytic Formal Thiolation of 2,5-Dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles in an Oil/Water Biphasic System.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(35),5826-5830.
MLA Chen, Ping,et al."Enantiomeric Catalytic Formal Thiolation of 2,5-Dimethyl-3-[1-(arylsulfonyl)alkyl]pyrroles in an Oil/Water Biphasic System".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .35(2016):5826-5830.
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