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Cobalt(III)-Catalyzed Regio- and Stereoselective alpha-Fluoroalkenylation of Arenes with gem-Difluorostyrenes
Kong, Lingheng1,2; Zhou, Xukai1,2; Li, Xingwei1
Source PublicationORGANIC LETTERS
2016-12-16
DOI10.1021/acs.orglett.6b03203
Volume18Issue:24Pages:6320-6323
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordC-H ACTIVATION ; REDOX-NEUTRAL SYNTHESIS ; BOND ACTIVATION ; MULTISUBSTITUTED ISOQUINOLINES ; MEDICINAL CHEMISTRY ; INTERNAL ALKYNES ; INDOLE SYNTHESIS ; ACCESS ; FUNCTIONALIZATION ; AMIDATION
AbstractA cobalt(III)-catalyzed alpha-fluoroalkenylation of different arenes with readily available gem-difluorostyrenes has been realized under mild and redox-neutral conditions. This reaction occurs via a C-H activation pathway and offers a step-economical access to various 1,2-diaryl-substituted monofluoroalkenes in excellent Z selectivity in moderate to excellent yields.
Language英语
WOS IDWOS:000390180300027
Citation statistics
Cited Times:53[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/151827
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Kong, Lingheng,Zhou, Xukai,Li, Xingwei. Cobalt(III)-Catalyzed Regio- and Stereoselective alpha-Fluoroalkenylation of Arenes with gem-Difluorostyrenes[J]. ORGANIC LETTERS,2016,18(24):6320-6323.
APA Kong, Lingheng,Zhou, Xukai,&Li, Xingwei.(2016).Cobalt(III)-Catalyzed Regio- and Stereoselective alpha-Fluoroalkenylation of Arenes with gem-Difluorostyrenes.ORGANIC LETTERS,18(24),6320-6323.
MLA Kong, Lingheng,et al."Cobalt(III)-Catalyzed Regio- and Stereoselective alpha-Fluoroalkenylation of Arenes with gem-Difluorostyrenes".ORGANIC LETTERS 18.24(2016):6320-6323.
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