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题名: Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review
作者: Li, Lin1;  Lin, Jian1;  Li, Xiaoyu1, 2;  Wang, Aiqin1;  Wang, Xiaodong1;  Zhang, Tao1
关键词: Catalysis ;  Microcalorimetry ;  Reactivity ;  Energetics ;  Binding strength ;  Catalyst characterization
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2016-12-01
DOI: 10.1016/S1872-2067(16)62578-0
卷: 37, 期:12, 页:2039-2052
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The formations and transformations of the chemical bonds of reactants and intermediates on catalyst surfaces occur in conjunction with the evolution of heat during catalytic reactions. Measurement of this evolved heat is helpful in terms of understanding the nature of the interactions between the catalyst and the adsorbed species, and provides insights into the reactivity of the catalyst. Although various techniques have previously been applied to assessments of evolved heat, direct measurements using a Tian-Calvet microcalorimeter are currently the most reliable method for this purpose. In this review, we summarize the relationship between the adsorption/reaction energetics determined by microcalorimetry and the reactivrties of supported catalysts, and examine the important role of microcalorimetry in understanding catalytic performance from the energetic point of view. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: ACID-BASE PROPERTIES ;  POLYCRYSTALLINE GOLD CATALYSTS ;  TEMPERATURE CO OXIDATION ;  N-BUTANE ISOMERIZATION ;  GAS-PHASE DEHYDRATION ;  SULFATED ZIRCONIA ;  NICKEL-CATALYSTS ;  ISOBUTANE DEHYDROGENATION ;  HETEROGENEOUS CATALYSIS ;  TUNGSTATED ZIRCONIA
语种: 英语
WOS记录号: WOS:000391777500001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/151860
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Li, Lin,Lin, Jian,Li, Xiaoyu,et al. Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(12):2039-2052.
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