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Immobilising a cobalt cubane catalyst on a dyesensitised TiO2 photoanode via electrochemical polymerisation for light-driven water oxidation
Li, Jialing1; Jiang, Yi1,2; Zhang, Qian1; Zhao, Xiaochen3; Li, Na1,4; Tong, Haili1; Yang, Xiaoxuan1; Xia, Lixin1
Source PublicationRSC ADVANCES
2017
DOI10.1039/c6ra24989b
Volume7Issue:7Pages:4102-4107
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordPHOTOELECTROCHEMICAL CELLS ; HYDROGEN-PRODUCTION ; ELECTRON-TRANSFER ; PHOTOSYSTEM-II ; BLUE DIMER ; COMPLEXES ; PHOTOSYNTHESIS ; MECHANISMS ; BILAYER ; OXIDES
AbstractA simple and effective method to prepare photocatalytically active electrodes for water oxidation is described in this paper. The precious-metal-free catalyst, Co4O4(O2CMe) 4(4-vinylpy) 4 (py = pyridine) was electrochemically polymerised on a RuP-sensitised TiO2 (RuP = [Ru(bpy) 2(4,4'-(PO3H2)(2)bpy(2))]Cl-2) and on a TiO2 surface codecorated with vinyl phosphate (Vpa) and RuP for applications in molecular photoelectrochemical (PEC) devices. With a Vpa chain as the anchoring group, the photoanode poly-Co4O4+Vpa/RuP/TiO2 demonstrated a significantly higher PEC performance compared to poly-Co4O4/RuP/TiO2. The introduction of a Vpa chain allows better immobilisation of catalyst and enhances the electron transport between the photosensitiser and the catalyst. A photocurrent density of similar to 100 mA cm(-2) was achieved in a Na2SO4 solution at pH 7.0 under a 0.4 V external bias, with a faradaic efficiency of 76% for oxygen production.
Language英语
WOS IDWOS:000393750100061
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/151892
Collection中国科学院大连化学物理研究所
Affiliation1.Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China
2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
4.Yingkou Inst Technol, Dept Chem Engn, Yingkou 115000, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Li, Jialing,Jiang, Yi,Zhang, Qian,et al. Immobilising a cobalt cubane catalyst on a dyesensitised TiO2 photoanode via electrochemical polymerisation for light-driven water oxidation[J]. RSC ADVANCES,2017,7(7):4102-4107.
APA Li, Jialing.,Jiang, Yi.,Zhang, Qian.,Zhao, Xiaochen.,Li, Na.,...&Xia, Lixin.(2017).Immobilising a cobalt cubane catalyst on a dyesensitised TiO2 photoanode via electrochemical polymerisation for light-driven water oxidation.RSC ADVANCES,7(7),4102-4107.
MLA Li, Jialing,et al."Immobilising a cobalt cubane catalyst on a dyesensitised TiO2 photoanode via electrochemical polymerisation for light-driven water oxidation".RSC ADVANCES 7.7(2017):4102-4107.
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