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Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography
Wang, Xin1,2; Lamprou, Alexandros2; Svec, Frantisek2; Bai, Yu1; Liu, Huwei1
关键词Chiral Stationary Phases Enantioselectivity Nano-liquid Chromatography Metal-organic Frameworks Polymer Monoliths
刊名JOURNAL OF SEPARATION SCIENCE
2016-12-01
DOI10.1002/jssc.201600810
39期:23页:4544-4548
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical
研究领域[WOS]Chemistry
关键词[WOS]STATIONARY-PHASE ; MASS-SPECTROMETRY ; SMALL MOLECULES ; SEPARATION ; MICROEXTRACTION ; PERFORMANCE
英文摘要A new approach to the preparation of enantioselective porous polymer monolithic columns with incorporated chiral metal-organic framework for nano-liquid chromatography has been developed. While no enantioseparation was achieved with monolithic poly(4-vinylpyridine-co-ethylene dimethacrylate) column, excellent separations of both enantiomers of (+/-)methyl phenyl sulfoxide were achieved with its counterpart prepared after admixing metalorganic framework [Zn-2(benzene dicarboxylate)(l-lactic acid)(dmf)], which is synthesized from zinc nitrate, L-lactic acid, and benzene dicarboxylic acid in the polymerization mixture. These novel monolithic columns combined selectivity of the chiral framework with the excellent hydrodynamic properties of polymer monoliths, may provide a great impact on future studies in the field of chiral analysis by liquid chromatography.
语种英语
WOS记录号WOS:000393030100009
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/151899
专题中国科学院大连化学物理研究所
作者单位1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Inst Analyt Chem,Coll Chem & Mol Engn, Beijing, Peoples R China
2.EO Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA
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GB/T 7714
Wang, Xin,Lamprou, Alexandros,Svec, Frantisek,et al. Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography[J]. JOURNAL OF SEPARATION SCIENCE,2016,39(23):4544-4548.
APA Wang, Xin,Lamprou, Alexandros,Svec, Frantisek,Bai, Yu,&Liu, Huwei.(2016).Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography.JOURNAL OF SEPARATION SCIENCE,39(23),4544-4548.
MLA Wang, Xin,et al."Polymer-based monolithic column with incorporated chiral metal-organic framework for enantioseparation of methyl phenyl sulfoxide using nano-liquid chromatography".JOURNAL OF SEPARATION SCIENCE 39.23(2016):4544-4548.
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