DICP OpenIR
Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates
Wang, Tao1,3; Wang, Wenlong1; Lyu, Yuan1; Chen, Xingkun1,3; Li, Cunyao1,3; Zhang, Yan1,3; Song, Xiangen1; Ding, Yunjie1,2
刊名RSC ADVANCES
2017
DOI10.1039/c6ra26780g
7期:5页:2836-2841
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]MILD CONDITIONS ; CYCLOADDITION ; EPOXIDES ; FIXATION ; DIOXIDE
英文摘要A series of cross-linked polymer supported ionic liquids based on quaternary ammonium salts have been prepared using a facile method of radical polymerization. Styrene-functionalized quaternary ammonium chloride salts, which are derived from imidazole, trimethylamine, triethylamine and triethanolamine, were copolymerized with divinyl benzene (DVB) under solvothermal conditions. These polymer supported ionic liquids displayed high efficiency in catalytic conversion of CO2 to cyclic carbonates. Notably, to the best of our knowledge, it was the first time that the polymeric ionic liquid catalyst was applied in a continuous flow fixed-bed reactor. During the study period of 130 hours, the polymer supported ionic liquids exhibited high stability.
语种英语
WOS记录号WOS:000393748600051
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/151900
专题中国科学院大连化学物理研究所
作者单位1.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
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GB/T 7714
Wang, Tao,Wang, Wenlong,Lyu, Yuan,et al. Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates[J]. RSC ADVANCES,2017,7(5):2836-2841.
APA Wang, Tao.,Wang, Wenlong.,Lyu, Yuan.,Chen, Xingkun.,Li, Cunyao.,...&Ding, Yunjie.(2017).Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates.RSC ADVANCES,7(5),2836-2841.
MLA Wang, Tao,et al."Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates".RSC ADVANCES 7.5(2017):2836-2841.
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