DICP OpenIR
Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates
Wang, Tao1,3; Wang, Wenlong1; Lyu, Yuan1; Chen, Xingkun1,3; Li, Cunyao1,3; Zhang, Yan1,3; Song, Xiangen1; Ding, Yunjie1,2
Source PublicationRSC ADVANCES
2017
DOI10.1039/c6ra26780g
Volume7Issue:5Pages:2836-2841
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordMILD CONDITIONS ; CYCLOADDITION ; EPOXIDES ; FIXATION ; DIOXIDE
AbstractA series of cross-linked polymer supported ionic liquids based on quaternary ammonium salts have been prepared using a facile method of radical polymerization. Styrene-functionalized quaternary ammonium chloride salts, which are derived from imidazole, trimethylamine, triethylamine and triethanolamine, were copolymerized with divinyl benzene (DVB) under solvothermal conditions. These polymer supported ionic liquids displayed high efficiency in catalytic conversion of CO2 to cyclic carbonates. Notably, to the best of our knowledge, it was the first time that the polymeric ionic liquid catalyst was applied in a continuous flow fixed-bed reactor. During the study period of 130 hours, the polymer supported ionic liquids exhibited high stability.
Language英语
WOS IDWOS:000393748600051
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/151900
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Wang, Tao,Wang, Wenlong,Lyu, Yuan,et al. Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates[J]. RSC ADVANCES,2017,7(5):2836-2841.
APA Wang, Tao.,Wang, Wenlong.,Lyu, Yuan.,Chen, Xingkun.,Li, Cunyao.,...&Ding, Yunjie.(2017).Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates.RSC ADVANCES,7(5),2836-2841.
MLA Wang, Tao,et al."Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates".RSC ADVANCES 7.5(2017):2836-2841.
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