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Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus
Li, Jie1; Sun, Jian1,2; Fan, Ronggang3; Yoneyama, Yoshiharu1; Yang, Guohui1; Tsubaki, Noritatsu1
关键词Anderson-schulz-flory Distribution Biomass Fischer-tropsch Synthesis Gasification Jet Fuel
刊名CHEMCATCHEM
2017-07-24
DOI10.1002/cctc.201700059
9期:14页:2668-2674
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]FISCHER-TROPSCH SYNTHESIS ; BIMODAL CATALYST ; COBALT ; CONVERSION ; NANOPARTICLES ; DEACTIVATION ; HYDROCARBONS ; PRODUCT
英文摘要Jet fuel is not easy to synthesize by the biomass-to-liquid (BTL) process owing to the limitation of the Anderson-Schulz-Flory (ASF) hydrocarbon distribution law in Fischer-Tropsch synthesis (FTS) with biomass-derived syngas (CO+H2). Here, we realized an anti-ASF distribution to selectively produce jet fuel from biomass on a large scale by addition of small amounts of 1-olefin, a FTS product, into syngas, enhancing jet fuel selectivity in hydrocarbons up to 64% and that in oil product to as high as 91%. The Co/SiO2 catalyst (300 g) was loaded into a flow-type three-phase reactor and 120h continuous operation was conducted by using the real-time on-line biomass- derived syngas from an entrained bed gasifier of biomass (240 kg day(-1)) of Mitsubishi Heavy Industries, Ltd. The production rate of liquid oil reached 720 g kg(cat)(-1)h(-1). The structure of the fresh and used catalyst was characterized in detail, accompanied with lab-scale data on reaction performance and catalyst properties. The stable technology process from biomass gasification to FTS, stable catalyst structure, and novel design of 1-olefin addition are the key to success in selectively converting biomass to jet fuel on a large scale.
语种英语
WOS记录号WOS:000406243100010
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/151904
专题中国科学院大连化学物理研究所
作者单位1.Univ Toyama, Dept Appl Chem, Sch Engn, Gofuku 3190, Toyama 9308555, Japan
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China
3.Shinka Co Ltd, Gofuku 3383-4, Toyama, Japan
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Li, Jie,Sun, Jian,Fan, Ronggang,et al. Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus[J]. CHEMCATCHEM,2017,9(14):2668-2674.
APA Li, Jie,Sun, Jian,Fan, Ronggang,Yoneyama, Yoshiharu,Yang, Guohui,&Tsubaki, Noritatsu.(2017).Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus.CHEMCATCHEM,9(14),2668-2674.
MLA Li, Jie,et al."Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus".CHEMCATCHEM 9.14(2017):2668-2674.
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