中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus
作者: Li, Jie1;  Sun, Jian1, 2;  Fan, Ronggang3;  Yoneyama, Yoshiharu1;  Yang, Guohui1;  Tsubaki, Noritatsu1
关键词: Anderson-Schulz-Flory distribution ;  biomass ;  Fischer-Tropsch synthesis ;  gasification ;  jet fuel
刊名: CHEMCATCHEM
发表日期: 2017-07-24
DOI: 10.1002/cctc.201700059
卷: 9, 期:14, 页:2668-2674
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Jet fuel is not easy to synthesize by the biomass-to-liquid (BTL) process owing to the limitation of the Anderson-Schulz-Flory (ASF) hydrocarbon distribution law in Fischer-Tropsch synthesis (FTS) with biomass-derived syngas (CO+H2). Here, we realized an anti-ASF distribution to selectively produce jet fuel from biomass on a large scale by addition of small amounts of 1-olefin, a FTS product, into syngas, enhancing jet fuel selectivity in hydrocarbons up to 64% and that in oil product to as high as 91%. The Co/SiO2 catalyst (300 g) was loaded into a flow-type three-phase reactor and 120h continuous operation was conducted by using the real-time on-line biomass- derived syngas from an entrained bed gasifier of biomass (240 kg day(-1)) of Mitsubishi Heavy Industries, Ltd. The production rate of liquid oil reached 720 g kg(cat)(-1)h(-1). The structure of the fresh and used catalyst was characterized in detail, accompanied with lab-scale data on reaction performance and catalyst properties. The stable technology process from biomass gasification to FTS, stable catalyst structure, and novel design of 1-olefin addition are the key to success in selectively converting biomass to jet fuel on a large scale.
关键词[WOS]: FISCHER-TROPSCH SYNTHESIS ;  BIMODAL CATALYST ;  COBALT ;  CONVERSION ;  NANOPARTICLES ;  DEACTIVATION ;  HYDROCARBONS ;  PRODUCT
语种: 英语
WOS记录号: WOS:000406243100010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/151904
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Univ Toyama, Dept Appl Chem, Sch Engn, Gofuku 3190, Toyama 9308555, Japan
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China
3.Shinka Co Ltd, Gofuku 3383-4, Toyama, Japan

Recommended Citation:
Li, Jie,Sun, Jian,Fan, Ronggang,et al. Selectively Converting Biomass to Jet Fuel in Large-scale Apparatus[J]. CHEMCATCHEM,2017,9(14):2668-2674.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Li, Jie]'s Articles
 [Sun, Jian]'s Articles
 [Fan, Ronggang]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Li, Jie]‘s Articles
 [Sun, Jian]‘s Articles
 [Fan, Ronggang]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace