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Investigation on Production of Cluster Ions Using Surface-Assisted Laser Desorption/Ionization Mass Spectrometry
Nie Long-Hui1; Wang Wei-Guo2
KeywordSurface-assisted Laser Desorption/ionization Mass Spectrometry Polycyclic Aromatic Ionization Pi-pi Bond Interaction Spatial Barrier
Source PublicationCHINESE JOURNAL OF ANALYTICAL CHEMISTRY
2017-06-01
DOI10.1016/S1872-2040(17)61020-X
Volume45Issue:6Pages:851-855
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical
WOS Research AreaChemistry
WOS KeywordMOLECULAR-WEIGHT DISTRIBUTIONS ; DESORPTION IONIZATION ; PETROLEUM ASPHALTENES ; SALDI-MS ; TOF-MS ; TIO2 NANOCRYSTALS ; NANOPARTICLES ; MATRIX ; SIZE
AbstractSurface-assisted laser desorption/ionization mass spectrometry (SALDI-MS) has become an indispensable tool in analysis of macromolecule and small molecule in solid and liquid samples. However, there were few studies focusing on the ionization mechanisms especially for the small molecules. In this work, the compounds of pyrene, coronene and rubrene with similar molecular structures were used to investigate the ionization mechanism via SALDI-MS. Additionally, the effect of laser power on product ions was also investigated. It was found that strong cluster ions peaks nM(+) (M = pyrene, coronene) were observed for pyrene and coronene, and daughter ions of coronene by loss of C2H2 were also observed. On the contrary, no cluster ion was obtained for rubrene, only daughter ions with the losses of nC(6)H(5) (n = 1, 2, 3) were acquired. Finally, the ionization mechanism was discussed. The formation of clusters of pyrene and coronene was attributed to the interaction of pi-pi bonds. For rubrene, the spatial barrier weakened the interaction of pi-pi bonds because the four phenyl groups were not on the same plane of skeleton structure, thus impeding the formation of cluster ions.
Language英语
WOS IDWOS:000406222800005
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/151908
Collection中国科学院大连化学物理研究所
Affiliation1.Hubei Univ Technol, Dept Mat & Chem Engn, Wuhan 430068, Hubei, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Nie Long-Hui,Wang Wei-Guo. Investigation on Production of Cluster Ions Using Surface-Assisted Laser Desorption/Ionization Mass Spectrometry[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2017,45(6):851-855.
APA Nie Long-Hui,&Wang Wei-Guo.(2017).Investigation on Production of Cluster Ions Using Surface-Assisted Laser Desorption/Ionization Mass Spectrometry.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,45(6),851-855.
MLA Nie Long-Hui,et al."Investigation on Production of Cluster Ions Using Surface-Assisted Laser Desorption/Ionization Mass Spectrometry".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 45.6(2017):851-855.
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