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Iridium-catalyzed asymmetric hydrogenation of cyclic iminium salts
Ji, Yue1,2; Feng, Guang-Shou1; Chen, Mu-Wang1; Shi, Lei1,3; Du, Haifeng3; Zhou, Yong-Gui1
刊名ORGANIC CHEMISTRY FRONTIERS
2017-06-01
DOI10.1039/c7qo00060j
4期:6页:1125-1129
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]BETA-CARBOLINE ALKALOIDS ; N-H IMINES ; ENANTIOSELECTIVE SYNTHESIS ; HETEROAROMATIC-COMPOUNDS ; PYRIDINIUM SALTS ; PAENIBACILLUS-LACTIS ; (R)-IMINE REDUCTASE ; AQUEOUS-MEDIA ; ANION-BINDING ; TETRAHYDROISOQUINOLINE
英文摘要An enantioselective hydrogenation of cyclic iminium salts has been successfully realized by employing [Ir(COD)Cl](2) and chiral diphosphine ligands as catalyst, furnishing chiral N-alkyl tetrahydroisoquinolines and N-alkyl tetrahydro-beta-carbolines with up to 96% ee and 88% ee, respectively. The hydrogenation provides a direct, simple and efficient protocol toward chiral tertiary amines. Meanwhile, asymmetric hydrogenation at the gram scale was also conducted smoothly without loss of reactivity and enantioselectivity.
语种英语
WOS记录号WOS:000405862600033
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/151911
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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GB/T 7714
Ji, Yue,Feng, Guang-Shou,Chen, Mu-Wang,et al. Iridium-catalyzed asymmetric hydrogenation of cyclic iminium salts[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(6):1125-1129.
APA Ji, Yue,Feng, Guang-Shou,Chen, Mu-Wang,Shi, Lei,Du, Haifeng,&Zhou, Yong-Gui.(2017).Iridium-catalyzed asymmetric hydrogenation of cyclic iminium salts.ORGANIC CHEMISTRY FRONTIERS,4(6),1125-1129.
MLA Ji, Yue,et al."Iridium-catalyzed asymmetric hydrogenation of cyclic iminium salts".ORGANIC CHEMISTRY FRONTIERS 4.6(2017):1125-1129.
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