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Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones
Liu, Bingxian1; Hu, Panjie1; Zhou, Xukai2; Bai, Dachang1; Chang, Junbiao1; Li, Xingwei1,2
Source PublicationORGANIC LETTERS
2017-04-21
DOI10.1021/acs.orglett.7b00690
Volume19Issue:8Pages:2086-2089
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordC-H BOND ; CATALYZED CASCADE CYCLIZATION ; ROOM-TEMPERATURE ; INTERMOLECULAR AMIDATION ; CONVERGENT SYNTHESIS ; RHODIUM(III)-CATALYZED AMIDATION ; NUCLEOPHILIC-ADDITION ; CONJUGATE ADDITION ; CARBONYL-COMPOUNDS ; DIRECTING GROUPS
AbstractA Rh(III)-catalyzed addition of benzylic C(sp(3))-H bond to alpha,beta-unsaturated ketones/aldehydes has been realized, leading to efficient synthesis of gamma-aryl ketones/aldehydes. This atom-economic reaction proceeded under mild and redox-neutral conditions with a broad substrate scope. Besides benzylic C-H, allylic C-H bonds are also applicable when assisted by O-methyl ketoxime directing groups.
Language英语
WOS IDWOS:000400123600038
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/151966
Collection中国科学院大连化学物理研究所
Affiliation1.Henan Normal Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Xinxiang 453007, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Bingxian,Hu, Panjie,Zhou, Xukai,et al. Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones[J]. ORGANIC LETTERS,2017,19(8):2086-2089.
APA Liu, Bingxian,Hu, Panjie,Zhou, Xukai,Bai, Dachang,Chang, Junbiao,&Li, Xingwei.(2017).Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones.ORGANIC LETTERS,19(8),2086-2089.
MLA Liu, Bingxian,et al."Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones".ORGANIC LETTERS 19.8(2017):2086-2089.
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