题名: Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones 作者: Liu, Bingxian 1 ; Hu, Panjie 1 ; Zhou, Xukai 2 ; Bai, Dachang 1 ; Chang, Junbiao 1 ; Li, Xingwei 1, 2
刊名: ORGANIC LETTERS
发表日期: 2017-04-21
DOI: 10.1021/acs.orglett.7b00690
卷: 19, 期: 8, 页: 2086-2089 收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology
; Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A Rh(III)-catalyzed addition of benzylic C(sp(3))-H bond to alpha,beta-unsaturated ketones/aldehydes has been realized, leading to efficient synthesis of gamma-aryl ketones/aldehydes. This atom-economic reaction proceeded under mild and redox-neutral conditions with a broad substrate scope. Besides benzylic C-H, allylic C-H bonds are also applicable when assisted by O-methyl ketoxime directing groups. 关键词[WOS]: C-H BOND
; CATALYZED CASCADE CYCLIZATION
; ROOM-TEMPERATURE
; INTERMOLECULAR AMIDATION
; CONVERGENT SYNTHESIS
; RHODIUM(III)-CATALYZED AMIDATION
; NUCLEOPHILIC-ADDITION
; CONJUGATE ADDITION
; CARBONYL-COMPOUNDS
; DIRECTING GROUPS
语种: 英语
WOS记录号: WOS:000400123600038
Citation statistics:
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/151966
Appears in Collections: 中国科学院大连化学物理研究所_期刊论文
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作者单位: 1.Henan Normal Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Xinxiang 453007, Peoples R China
Recommended Citation:
Liu, Bingxian,Hu, Panjie,Zhou, Xukai,et al. Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones[J]. ORGANIC LETTERS,2017,19(8):2086-2089.
