Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones

doi:10.1021/acs.orglett.7b00690

DICP OpenIR

	*CpRh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones**
	Liu, Bingxian 1; Hu, Panjie 1; Zhou, Xukai 2; Bai, Dachang 1; Chang, Junbiao 1; Li, Xingwei 1,2
Source Publication	ORGANIC LETTERS
	2017-04-21
DOI	10.1021/acs.orglett.7b00690
Volume	19 Issue:8 Pages:2086-2089
Indexed By	SCI
Subtype	Article
WOS Headings	Science & Technology ; Physical Sciences
WOS Subject	Chemistry, Organic
WOS Research Area	Chemistry
WOS Keyword	C-H BOND ; CATALYZED CASCADE CYCLIZATION ; ROOM-TEMPERATURE ; INTERMOLECULAR AMIDATION ; CONVERGENT SYNTHESIS ; RHODIUM(III)-CATALYZED AMIDATION ; NUCLEOPHILIC-ADDITION ; CONJUGATE ADDITION ; CARBONYL-COMPOUNDS ; DIRECTING GROUPS
Abstract	A Rh(III)-catalyzed addition of benzylic C(sp(3))-H bond to alpha,beta-unsaturated ketones/aldehydes has been realized, leading to efficient synthesis of gamma-aryl ketones/aldehydes. This atom-economic reaction proceeded under mild and redox-neutral conditions with a broad substrate scope. Besides benzylic C-H, allylic C-H bonds are also applicable when assisted by O-methyl ketoxime directing groups.
Language	英语
WOS ID	WOS:000400123600038
Citation statistics
Document Type	期刊论文
Identifier	http://cas-ir.dicp.ac.cn/handle/321008/151966
Collection	中国科学院大连化学物理研究所
Affiliation	1.Henan Normal Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation GB/T 7714	Liu, Bingxian,Hu, Panjie,Zhou, Xukai,et al. Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones[J]. ORGANIC LETTERS,2017,19(8):2086-2089.
APA	Liu, Bingxian,Hu, Panjie,Zhou, Xukai,Bai, Dachang,Chang, Junbiao,&Li, Xingwei.(2017).Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones.ORGANIC LETTERS,19(8),2086-2089.
MLA	Liu, Bingxian,et al."Cp*Rh(III)-Catalyzed Mild Addition of C(sp(3))-H Bonds to alpha,beta-Unsaturated Aldehydes and Ketones".ORGANIC LETTERS 19.8(2017):2086-2089.

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