DICP OpenIR
Different locations of adenine in AOT and CTAB reverse micelles
Luo, Jian1,2; Liu, Yan1,2; Yang, Songqiu1
Source PublicationJOURNAL OF MOLECULAR LIQUIDS
2017-04-01
DOI10.1016/j.molliq.2017.02.067
Volume232Pages:236-242
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordMOLECULAR-DYNAMICS SIMULATIONS ; NANOCONFINED WATER ; ATOMIC CHARGES ; NUCLEIC-ACIDS ; FLUORESCENCE ; SPECTROSCOPY ; SYSTEM ; MODEL ; SIZE ; MICROEMULSIONS
AbstractWe explore the locations of adenine encapsulated in the anionic Aerosol-OT (AOT) and cationic cetyltrimethylammonium bromide (CTAB) reverse micelles (RMs) utilizing steady-state spectroscopy and molecular dynamics simulations. In AOT RMs with various water contents, adenine forms stacked conformers at the AOT/water interface, determined by the appearance of emission from adenine excimers and molecular dynamics simulations. In contrast, adenine resides in the water core of CTAB RMs without the formation of stacked conformers. The interbase distance of stacked adenines at the AOT/water interface has a significant fluctuation, especially in RMs of low water content. Hydrogen bonding interactions between adenine and AOT molecules play a role in the formation of stacked adenines. (C) 2017 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000399507400026
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/151974
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, DICP, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China
Recommended Citation
GB/T 7714
Luo, Jian,Liu, Yan,Yang, Songqiu. Different locations of adenine in AOT and CTAB reverse micelles[J]. JOURNAL OF MOLECULAR LIQUIDS,2017,232:236-242.
APA Luo, Jian,Liu, Yan,&Yang, Songqiu.(2017).Different locations of adenine in AOT and CTAB reverse micelles.JOURNAL OF MOLECULAR LIQUIDS,232,236-242.
MLA Luo, Jian,et al."Different locations of adenine in AOT and CTAB reverse micelles".JOURNAL OF MOLECULAR LIQUIDS 232(2017):236-242.
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