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Environmentally benign and economic synthesis of covalent triazine-based frameworks
Zhang, Ling1,2; Liu, Xue2; Yang, Rui-Xia2; Huang, Nian-Yu1; Deng, Wei-Qiao2
KeywordCovalent Triazine-based Framework Aryl Bromide Cyanation Potassium Hexacyanoferrate(Ii) Palladium Acetate
Source PublicationCHINESE JOURNAL OF CATALYSIS
2017-03-01
DOI10.1016/S1872-2067(17)62771-2
Volume38Issue:3Pages:583-588
Indexed BySCI ; ISTP
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordPALLADIUM-CATALYZED CYANATION ; METAL-FREE ELECTROCATALYSTS ; OXYGEN REDUCTION REACTION ; ORGANIC FRAMEWORKS ; ARYL CHLORIDES ; CO2 ; POLYMER ; CARBON ; CAPTURE ; STORAGE
AbstractCovalent triazine-based frameworks (CTFs) are important microporous materials with a wide range of applications. Here, we demonstrate an environmentally benign and economic synthetic pathway to CTFs. The monomers used for CTFs, aromatic nitriles, were obtained by cyanation using nontoxic potassium hexacyanoferrate(II) in place of commonly used toxic cyanides. Then, the CTFs were synthesized by trimerization of the corresponding cyano monomers in molten zinc chloride. A series of CTFs was synthesized, and the highest Brunauer-Emmett-Teller surface area measured in this series was 2404 m(2)/g. Among the synthesized CTFs, CTFDCP exhibited excellent CO2 adsorption properties, with a CO2 uptake of 225 mg/g at 0 degrees C. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000400125100020
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/151992
Collection中国科学院大连化学物理研究所
Affiliation1.China Three Gorges Univ, Coll Biol & Pharmaceut Sci, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Ling,Liu, Xue,Yang, Rui-Xia,et al. Environmentally benign and economic synthesis of covalent triazine-based frameworks[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(3):583-588.
APA Zhang, Ling,Liu, Xue,Yang, Rui-Xia,Huang, Nian-Yu,&Deng, Wei-Qiao.(2017).Environmentally benign and economic synthesis of covalent triazine-based frameworks.CHINESE JOURNAL OF CATALYSIS,38(3),583-588.
MLA Zhang, Ling,et al."Environmentally benign and economic synthesis of covalent triazine-based frameworks".CHINESE JOURNAL OF CATALYSIS 38.3(2017):583-588.
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