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Environmentally benign and economic synthesis of covalent triazine-based frameworks
Zhang, Ling1,2; Liu, Xue2; Yang, Rui-Xia2; Huang, Nian-Yu1; Deng, Wei-Qiao2
关键词Covalent Triazine-based Framework Aryl Bromide Cyanation Potassium Hexacyanoferrate(Ii) Palladium Acetate
刊名CHINESE JOURNAL OF CATALYSIS
2017-03-01
DOI10.1016/S1872-2067(17)62771-2
38期:3页:583-588
收录类别SCI ; ISTP
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]PALLADIUM-CATALYZED CYANATION ; METAL-FREE ELECTROCATALYSTS ; OXYGEN REDUCTION REACTION ; ORGANIC FRAMEWORKS ; ARYL CHLORIDES ; CO2 ; POLYMER ; CARBON ; CAPTURE ; STORAGE
英文摘要Covalent triazine-based frameworks (CTFs) are important microporous materials with a wide range of applications. Here, we demonstrate an environmentally benign and economic synthetic pathway to CTFs. The monomers used for CTFs, aromatic nitriles, were obtained by cyanation using nontoxic potassium hexacyanoferrate(II) in place of commonly used toxic cyanides. Then, the CTFs were synthesized by trimerization of the corresponding cyano monomers in molten zinc chloride. A series of CTFs was synthesized, and the highest Brunauer-Emmett-Teller surface area measured in this series was 2404 m(2)/g. Among the synthesized CTFs, CTFDCP exhibited excellent CO2 adsorption properties, with a CO2 uptake of 225 mg/g at 0 degrees C. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000400125100020
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/151992
专题中国科学院大连化学物理研究所
作者单位1.China Three Gorges Univ, Coll Biol & Pharmaceut Sci, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
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Zhang, Ling,Liu, Xue,Yang, Rui-Xia,et al. Environmentally benign and economic synthesis of covalent triazine-based frameworks[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(3):583-588.
APA Zhang, Ling,Liu, Xue,Yang, Rui-Xia,Huang, Nian-Yu,&Deng, Wei-Qiao.(2017).Environmentally benign and economic synthesis of covalent triazine-based frameworks.CHINESE JOURNAL OF CATALYSIS,38(3),583-588.
MLA Zhang, Ling,et al."Environmentally benign and economic synthesis of covalent triazine-based frameworks".CHINESE JOURNAL OF CATALYSIS 38.3(2017):583-588.
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