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Divergent Access to 1-Naphthols and Isocoumarins via Rh(III)-Catalyzed C-H Activation Assisted by Phosphonium Ylide
Li, Yunyun1,2; Wang, Qiang1,2; Yang, Xifa1,2; Xie, Fang1; Li, Xingwei1
Source PublicationORGANIC LETTERS
2017-07-07
DOI10.1021/acs.orglett.7b01365
Volume19Issue:13Pages:3410-3413
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordRHODIUM-CATALYZED ANNULATION ; TRACELESS DIRECTING GROUPS ; BOND FUNCTIONALIZATION ; OXIDATIVE ANNULATION ; RUBIA-CORDIFOLIA ; N BOND ; REGIOSELECTIVE SYNTHESIS ; SUBSTITUTED 1-NAPHTHOLS ; CLEAVAGE ; ALKYNES
AbstractRh-catalyzed C-H activation of phenacyl phosphoniums in coupling with alpha-diazocarbonyl compounds has been realized with the assistance of a mutifunctional phosphonium ylidic directing group, providing expedient accesses to 1-naphthols and isocoumarins. Switchable synthesis of 1-naphthols and isocoumarins was realized by substrate control, where these transformations were enabled by initial C-H activation and subsequent intramolecular Wittig reaction or nucleophilic C-O formation.
Language英语
WOS IDWOS:000405358300020
Citation statistics
Cited Times:28[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152030
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Yunyun,Wang, Qiang,Yang, Xifa,et al. Divergent Access to 1-Naphthols and Isocoumarins via Rh(III)-Catalyzed C-H Activation Assisted by Phosphonium Ylide[J]. ORGANIC LETTERS,2017,19(13):3410-3413.
APA Li, Yunyun,Wang, Qiang,Yang, Xifa,Xie, Fang,&Li, Xingwei.(2017).Divergent Access to 1-Naphthols and Isocoumarins via Rh(III)-Catalyzed C-H Activation Assisted by Phosphonium Ylide.ORGANIC LETTERS,19(13),3410-3413.
MLA Li, Yunyun,et al."Divergent Access to 1-Naphthols and Isocoumarins via Rh(III)-Catalyzed C-H Activation Assisted by Phosphonium Ylide".ORGANIC LETTERS 19.13(2017):3410-3413.
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