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Rhodium(III)-Catalyzed Acylation of C(sp(3))-H Bonds with Cyclopropenones
Kong, Lingheng1,2; Zhou, Xukai1,2; Xu, Youwei1,2; Li, Xingwei1
Source PublicationORGANIC LETTERS
2017-07-07
DOI10.1021/acs.orglett.7b01650
Volume19Issue:13Pages:3644-3647
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordC-H ACTIVATION ; INTERMOLECULAR AMIDATION ; ACTIVATION/CYCLOADDITION REACTIONS ; ALLYLATION REACTIONS ; N-PHENOXYACETAMIDE ; ROOM-TEMPERATURE ; DIRECTING GROUPS ; FUNCTIONALIZATION ; ARENES ; 8-METHYLQUINOLINES
AbstractRh(III)-catalyzed activation and acylation of sp(3) C-H bonds has been realized with diarylcyclopropenone as an acylating reagent. Both benzylic C-H in 8-methylquinolines and unactivated C-H in 2-alkylpyridines are applicable in this C-H acylation reaction, providing enones in good yields under redox-neutral conditions.
Language英语
WOS IDWOS:000405358300079
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152035
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Kong, Lingheng,Zhou, Xukai,Xu, Youwei,et al. Rhodium(III)-Catalyzed Acylation of C(sp(3))-H Bonds with Cyclopropenones[J]. ORGANIC LETTERS,2017,19(13):3644-3647.
APA Kong, Lingheng,Zhou, Xukai,Xu, Youwei,&Li, Xingwei.(2017).Rhodium(III)-Catalyzed Acylation of C(sp(3))-H Bonds with Cyclopropenones.ORGANIC LETTERS,19(13),3644-3647.
MLA Kong, Lingheng,et al."Rhodium(III)-Catalyzed Acylation of C(sp(3))-H Bonds with Cyclopropenones".ORGANIC LETTERS 19.13(2017):3644-3647.
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