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Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives
Shao, Long1,2; Hu, Xiang-Ping1
刊名CHEMICAL COMMUNICATIONS
2017-07-25
DOI10.1039/c7cc03034g
53期:58页:8192-8195
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ENANTIOSELECTIVE SYNTHESIS ; OXIDATIVE DEAROMATIZATION ; ALLYLIC DEAROMATIZATION ; NAPHTHOL DERIVATIVES ; BETA-NAPHTHOLS ; INTRAMOLECULAR DEAROMATIZATION ; SUBSTITUTION-REACTIONS ; 3+2 CYCLOADDITION ; ESTERS ; AMINATION
英文摘要A copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives has been realized. Under the catalysis of Cu(OTf)center dot 1/2C(6)H(6) decorated with a chiral tridentate ketimine P,N,N-ligand, the dearomatization reaction proceeded smoothly with excellent control of chemo-, regio-, and enantio-selectivities, thus providing a variety of optically active cyclohexadienone derivatives with up to > 99% ee.
语种英语
WOS记录号WOS:000405679100020
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152048
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Shao, Long,Hu, Xiang-Ping. Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives[J]. CHEMICAL COMMUNICATIONS,2017,53(58):8192-8195.
APA Shao, Long,&Hu, Xiang-Ping.(2017).Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives.CHEMICAL COMMUNICATIONS,53(58),8192-8195.
MLA Shao, Long,et al."Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives".CHEMICAL COMMUNICATIONS 53.58(2017):8192-8195.
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