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题名: Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives
作者: Shao, Long1, 2;  Hu, Xiang-Ping1
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2017-07-25
DOI: 10.1039/c7cc03034g
卷: 53, 期:58, 页:8192-8195
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives has been realized. Under the catalysis of Cu(OTf)center dot 1/2C(6)H(6) decorated with a chiral tridentate ketimine P,N,N-ligand, the dearomatization reaction proceeded smoothly with excellent control of chemo-, regio-, and enantio-selectivities, thus providing a variety of optically active cyclohexadienone derivatives with up to > 99% ee.
关键词[WOS]: ENANTIOSELECTIVE SYNTHESIS ;  OXIDATIVE DEAROMATIZATION ;  ALLYLIC DEAROMATIZATION ;  NAPHTHOL DERIVATIVES ;  BETA-NAPHTHOLS ;  INTRAMOLECULAR DEAROMATIZATION ;  SUBSTITUTION-REACTIONS ;  3+2 CYCLOADDITION ;  ESTERS ;  AMINATION
语种: 英语
WOS记录号: WOS:000405679100020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152048
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Shao, Long,Hu, Xiang-Ping. Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives[J]. CHEMICAL COMMUNICATIONS,2017,53(58):8192-8195.
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