DICP OpenIR
Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives
Shao, Long1,2; Hu, Xiang-Ping1
Source PublicationCHEMICAL COMMUNICATIONS
2017-07-25
DOI10.1039/c7cc03034g
Volume53Issue:58Pages:8192-8195
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordENANTIOSELECTIVE SYNTHESIS ; OXIDATIVE DEAROMATIZATION ; ALLYLIC DEAROMATIZATION ; NAPHTHOL DERIVATIVES ; BETA-NAPHTHOLS ; INTRAMOLECULAR DEAROMATIZATION ; SUBSTITUTION-REACTIONS ; 3+2 CYCLOADDITION ; ESTERS ; AMINATION
AbstractA copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives has been realized. Under the catalysis of Cu(OTf)center dot 1/2C(6)H(6) decorated with a chiral tridentate ketimine P,N,N-ligand, the dearomatization reaction proceeded smoothly with excellent control of chemo-, regio-, and enantio-selectivities, thus providing a variety of optically active cyclohexadienone derivatives with up to > 99% ee.
Language英语
WOS IDWOS:000405679100020
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152048
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Shao, Long,Hu, Xiang-Ping. Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives[J]. CHEMICAL COMMUNICATIONS,2017,53(58):8192-8195.
APA Shao, Long,&Hu, Xiang-Ping.(2017).Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives.CHEMICAL COMMUNICATIONS,53(58),8192-8195.
MLA Shao, Long,et al."Copper-catalyzed intermolecular asymmetric propargylic dearomatization of phenol derivatives".CHEMICAL COMMUNICATIONS 53.58(2017):8192-8195.
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