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A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters
Zhou Yang1,2; Li Gao1
关键词Gold Cluster Carbon-carbon Coupling Ligand Engineering Doping Effect Ullmann Coupling Sonogashira Cross-coupling Suzuki Cross-coupling a(3)-coupling
刊名ACTA PHYSICO-CHIMICA SINICA
2017-05-31
DOI10.3866/PKU.WHXB201704101
33页:1297-1309
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]AU-25 NANOCLUSTERS ; CHEMOSELECTIVE HYDROGENATION ; MULTICOMPONENT REACTIONS ; HETEROGENEOUS CATALYSTS ; SELECTIVE OXIDATION ; CRYSTAL-STRUCTURE ; C-C ; CLUSTERS ; NANOPARTICLES ; ACTIVATION
英文摘要Well-defined gold nanoclusters have been documented as new and promising materials in the field of nanoscience. They have been well explored for the nanocatalysis of reactions like selective oxidation and hydrogenation, carbon-carbon coupling, etc. These Au nanoclusters possess unique electronic properties and crystal structure, which provide an excellent opportunity to correlate atomic structure with intrinsic catalytic property and to investigate the mechanisms of reactions over Au nanoclusters. In this review, we generalize the catalytic application of gold nanoclusters in carbon-carbon coupling reactions, including Ullmann, Sonogashira, Suzuki, and A(3)-coupling reactions. Herein, we have discussed ligand engineering (e.g., aromatic and aliphatic thiolate) as well as the effect of metal dopants (e.g., Cu, Ag, Pt, and Pd). Finally, the tentative catalytic mechanisms and the structure-performance relationships were discussed at the atomic level, which will give some clue for the design of efficient gold cluster catalysts.
语种英语
WOS记录号WOS:000403249300008
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被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152102
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Zhou Yang,Li Gao. A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters[J]. ACTA PHYSICO-CHIMICA SINICA,2017,33:1297-1309.
APA Zhou Yang,&Li Gao.(2017).A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters.ACTA PHYSICO-CHIMICA SINICA,33,1297-1309.
MLA Zhou Yang,et al."A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters".ACTA PHYSICO-CHIMICA SINICA 33(2017):1297-1309.
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