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A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters
Zhou Yang1,2; Li Gao1
KeywordGold Cluster Carbon-carbon Coupling Ligand Engineering Doping Effect Ullmann Coupling Sonogashira Cross-coupling Suzuki Cross-coupling a(3)-coupling
Source PublicationACTA PHYSICO-CHIMICA SINICA
2017-05-31
DOI10.3866/PKU.WHXB201704101
Volume33Pages:1297-1309
Indexed BySCI
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordAU-25 NANOCLUSTERS ; CHEMOSELECTIVE HYDROGENATION ; MULTICOMPONENT REACTIONS ; HETEROGENEOUS CATALYSTS ; SELECTIVE OXIDATION ; CRYSTAL-STRUCTURE ; C-C ; CLUSTERS ; NANOPARTICLES ; ACTIVATION
AbstractWell-defined gold nanoclusters have been documented as new and promising materials in the field of nanoscience. They have been well explored for the nanocatalysis of reactions like selective oxidation and hydrogenation, carbon-carbon coupling, etc. These Au nanoclusters possess unique electronic properties and crystal structure, which provide an excellent opportunity to correlate atomic structure with intrinsic catalytic property and to investigate the mechanisms of reactions over Au nanoclusters. In this review, we generalize the catalytic application of gold nanoclusters in carbon-carbon coupling reactions, including Ullmann, Sonogashira, Suzuki, and A(3)-coupling reactions. Herein, we have discussed ligand engineering (e.g., aromatic and aliphatic thiolate) as well as the effect of metal dopants (e.g., Cu, Ag, Pt, and Pd). Finally, the tentative catalytic mechanisms and the structure-performance relationships were discussed at the atomic level, which will give some clue for the design of efficient gold cluster catalysts.
Language英语
WOS IDWOS:000403249300008
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152102
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhou Yang,Li Gao. A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters[J]. ACTA PHYSICO-CHIMICA SINICA,2017,33:1297-1309.
APA Zhou Yang,&Li Gao.(2017).A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters.ACTA PHYSICO-CHIMICA SINICA,33,1297-1309.
MLA Zhou Yang,et al."A Critical Review on Carbon-Carbon Coupling over Ultra-Small Gold Nanoclusters".ACTA PHYSICO-CHIMICA SINICA 33(2017):1297-1309.
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