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Substantial Intramolecular Charge Transfer Induces Long Emission Wavelengths and Mega Stokes Shifts in 6-Aminocoumarins
Liu, Xiaogang1,2,3; Cole, Jacqueline M.1,4,5,6; Xu, Zhaochao7
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY C
2017-06-22
DOI10.1021/acs.jpcc.7b04176
Volume121Pages:13274-13279
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS KeywordSENSITIZED SOLAR-CELLS ; COUMARIN DYES ; FLUORESCENT SENSOR ; EXCITED-STATE ; LASER-DYES ; SOLVENTS ; FLUOROPHORES ; DEACTIVATION ; SEPARATION ; EFFICIENCY
AbstractCoumarins are deployed in numerous bioimaging and biosensing applications. Among various coumarin derivatives, 6-aminocoumarins attract increasing attention for their red-shifted emissions, mega Stokes shifts, and significant solvatochromism. These spectral characteristics together with weak emission intensities have historically been ascribed to the formation of the twisted intramolecular charge transfer (TICT) state in 6-aminocoumarins. In this work, we demonstrate that it is actually substantial intramolecular Charge transfer (ICT) that is responsible for these fluorescent properties. Based on this new understanding, we reanalyzed the sensing mechanism of a 6-aminocouarmin based fluorescent probe and obtained close agreement with experimental data. Our results lead to a deeper understanding of the photophysics of 6-aminocoumarins and will inspire the rational development of novel fluorescent probes.
Language英语
WOS IDWOS:000404201900035
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152107
Collection中国科学院大连化学物理研究所
Affiliation1.Univ Cambridge, Dept Phys, Cavendish Lab, JJ Thomson Ave, Cambridge CB3 0HE, England
2.Singapore Univ Technol & Design, 8 Somapah Rd, Singapore 487372, Singapore
3.Singapore MIT Alliance Res & Technol SMART, 1 CREATE Way, Singapore 138602, Singapore
4.Univ Cambridge, Dept Chem Engn & Biotechnol, Philippa Fawcett Dr, Cambridge CB3 0AS, England
5.STFC Rutherford Appleton Lab, ISIS Neutron & Muon Facil, Harwell Sci & Innovat Campus, Didcot OX11 0QX, Oxon, England
6.Argonne Natl Lab, 9700 S Cass Ave, Argonne, IL 60439 USA
7.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, 457 Zhongshan Rd, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Xiaogang,Cole, Jacqueline M.,Xu, Zhaochao. Substantial Intramolecular Charge Transfer Induces Long Emission Wavelengths and Mega Stokes Shifts in 6-Aminocoumarins[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2017,121:13274-13279.
APA Liu, Xiaogang,Cole, Jacqueline M.,&Xu, Zhaochao.(2017).Substantial Intramolecular Charge Transfer Induces Long Emission Wavelengths and Mega Stokes Shifts in 6-Aminocoumarins.JOURNAL OF PHYSICAL CHEMISTRY C,121,13274-13279.
MLA Liu, Xiaogang,et al."Substantial Intramolecular Charge Transfer Induces Long Emission Wavelengths and Mega Stokes Shifts in 6-Aminocoumarins".JOURNAL OF PHYSICAL CHEMISTRY C 121(2017):13274-13279.
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