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Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water
Xu, Zhanwei; Yan, Peifang; Jiang, Hong; Liu, Kairui; Zhang, Z. Conrad
KeywordIridium Reductive Amination Hydrogenation Levulinic Acid Biomass
Source PublicationCHINESE JOURNAL OF CHEMISTRY
2017-05-01
DOI10.1002/cjoc.201600726
Volume35Pages:581-585
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordFUNCTIONAL BIPYRIDONATE LIGAND ; GAMMA-VALEROLACTONE ; DEHYDROGENATIVE OXIDATION ; FORMIC-ACID ; TRANSFER HYDROGENATION ; CO2 HYDROGENATION ; COMPLEX BEARING ; AQUEOUS-MEDIA ; BIOMASS ; ALCOHOLS
AbstractThe synthesis of pyrrolidinones from reductive amination of levulinic acid (LA) with primary amines is reported. Pyrrolidinones have various applications such as surfactants, pharmaceutical intermediates, dispersants, and solvents. The half-sandwich Cp* Ir complex (Cp* is 1,2,3,4,5-pentamethylcyclopenta-1,3-diene) coordinated by bipyridine ligand bearing both dimethylamino and ortho-hydroxyl groups showed high catalytic activity for the reductive amination of LA. A range of primary amines, such as aromatic and benzyl amines, were readily converted to corresponding pyrrolidinones in good yields.
Language英语
WOS IDWOS:000404028300009
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152109
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Xu, Zhanwei,Yan, Peifang,Jiang, Hong,et al. Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35:581-585.
APA Xu, Zhanwei,Yan, Peifang,Jiang, Hong,Liu, Kairui,&Zhang, Z. Conrad.(2017).Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water.CHINESE JOURNAL OF CHEMISTRY,35,581-585.
MLA Xu, Zhanwei,et al."Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water".CHINESE JOURNAL OF CHEMISTRY 35(2017):581-585.
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