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题名: Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water
作者: Xu, Zhanwei1;  Yan, Peifang1;  Jiang, Hong1;  Liu, Kairui1;  Zhang, Z. Conrad1
关键词: iridium ;  reductive amination ;  hydrogenation ;  levulinic acid ;  biomass
刊名: CHINESE JOURNAL OF CHEMISTRY
发表日期: 2017-05-01
DOI: 10.1002/cjoc.201600726
卷: 35, 页:581-585
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The synthesis of pyrrolidinones from reductive amination of levulinic acid (LA) with primary amines is reported. Pyrrolidinones have various applications such as surfactants, pharmaceutical intermediates, dispersants, and solvents. The half-sandwich Cp* Ir complex (Cp* is 1,2,3,4,5-pentamethylcyclopenta-1,3-diene) coordinated by bipyridine ligand bearing both dimethylamino and ortho-hydroxyl groups showed high catalytic activity for the reductive amination of LA. A range of primary amines, such as aromatic and benzyl amines, were readily converted to corresponding pyrrolidinones in good yields.
关键词[WOS]: FUNCTIONAL BIPYRIDONATE LIGAND ;  GAMMA-VALEROLACTONE ;  DEHYDROGENATIVE OXIDATION ;  FORMIC-ACID ;  TRANSFER HYDROGENATION ;  CO2 HYDROGENATION ;  COMPLEX BEARING ;  AQUEOUS-MEDIA ;  BIOMASS ;  ALCOHOLS
语种: 英语
WOS记录号: WOS:000404028300009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152109
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Xu, Zhanwei,Yan, Peifang,Jiang, Hong,et al. Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35:581-585.
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