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题名: Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans
作者: Lou, Jiang1, 2;  Wang, Quannan1, 2;  Wu, Kaikai1;  Wu, Ping1, 2;  Yu, Zhengkun1, 3
刊名: ORGANIC LETTERS
发表日期: 2017-06-16
DOI: 10.1021/acs.orglett.7b01431
卷: 19, 页:3287-3290
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Tetrasubstituted furans were efficiently synthesized from Fe(OAc)(2)-catalyzed C-H/C-H cross-dehydrogenative-coupling (CDC) reactions of activated carbonyl methylenes with S,S-functionalized internal olefins, that is, alpha-oxo ketene dithioacetals and analogues, under oxidative conditions. beta-Ketoesters, 1,3-dicarbonyls, beta-keto nitrile, and amide derivatives were used as the coupling partners. The resultant alkylthio- and carbonyl-functionalized furans could be further transformed to diverse arylated furan derivatives and furan-fused N-heterocycles, respectively. The control experiments have revealed a radical reaction pathway.
关键词[WOS]: OXO KETENE DITHIOACETALS ;  ONE-POT SYNTHESIS ;  BETA-KETO-ESTERS ;  POLYSUBSTITUTED FURANS ;  MULTISUBSTITUTED FURANS ;  REGIOSELECTIVE SYNTHESIS ;  SUBSTITUTED FURANS ;  1,3-DICARBONYL COMPOUNDS ;  EFFICIENT SYNTHESIS ;  ALKYL KETONES
语种: 英语
WOS记录号: WOS:000403854300063
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152122
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China

Recommended Citation:
Lou, Jiang,Wang, Quannan,Wu, Kaikai,et al. Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans[J]. ORGANIC LETTERS,2017,19:3287-3290.
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