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Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans
Lou, Jiang1,2; Wang, Quannan1,2; Wu, Kaikai1; Wu, Ping1,2; Yu, Zhengkun1,3
刊名ORGANIC LETTERS
2017-06-16
DOI10.1021/acs.orglett.7b01431
19页:3287-3290
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]OXO KETENE DITHIOACETALS ; ONE-POT SYNTHESIS ; BETA-KETO-ESTERS ; POLYSUBSTITUTED FURANS ; MULTISUBSTITUTED FURANS ; REGIOSELECTIVE SYNTHESIS ; SUBSTITUTED FURANS ; 1,3-DICARBONYL COMPOUNDS ; EFFICIENT SYNTHESIS ; ALKYL KETONES
英文摘要Tetrasubstituted furans were efficiently synthesized from Fe(OAc)(2)-catalyzed C-H/C-H cross-dehydrogenative-coupling (CDC) reactions of activated carbonyl methylenes with S,S-functionalized internal olefins, that is, alpha-oxo ketene dithioacetals and analogues, under oxidative conditions. beta-Ketoesters, 1,3-dicarbonyls, beta-keto nitrile, and amide derivatives were used as the coupling partners. The resultant alkylthio- and carbonyl-functionalized furans could be further transformed to diverse arylated furan derivatives and furan-fused N-heterocycles, respectively. The control experiments have revealed a radical reaction pathway.
语种英语
WOS记录号WOS:000403854300063
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152122
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China
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Lou, Jiang,Wang, Quannan,Wu, Kaikai,et al. Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans[J]. ORGANIC LETTERS,2017,19:3287-3290.
APA Lou, Jiang,Wang, Quannan,Wu, Kaikai,Wu, Ping,&Yu, Zhengkun.(2017).Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans.ORGANIC LETTERS,19,3287-3290.
MLA Lou, Jiang,et al."Iron-Catalyzed Oxidative C-H Functionalization of Internal Olefins for the Synthesis of Tetrasubstituted Furans".ORGANIC LETTERS 19(2017):3287-3290.
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