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题名: Palladium/Phosphorus-Doped Porous Organic Polymer as Recyclable Chemoselective and Efficient Hydrogenation Catalyst under Ambient Conditions
作者: Ding, Zong-Cang1;  Li, Cun-Yao2;  Chen, Jun-Jia1;  Zeng, Jia-Hao1;  Tang, Hai-Tao1;  Ding, Yun-Jie2;  Zhan, Zhuang-Ping1
关键词: heterogeneous catalysis ;  hydrogenation ;  indoles ;  nitroarenes ;  palladium nanoparticles ;  porous organic polymers
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2017-07-03
DOI: 10.1002/adsc.201700374
卷: 359, 页:2280-2287
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A new type of phosphorus-doped porous organic polymer (POP) has been readily synthesized through a Heck reaction, which could be used not only as a support but also a ligand for palladium nanoparticles. The dual-functional material supported palladium nanocatalyst was used for the efficient and chemoselective hydrogenation of varieties of nitroarenes and a, b-unsaturated compounds, as well as for the synthesis of indoles from 2-nitrophenylaceto-nitrile under 1 atm hydrogen in green solvents at room temperature. No obvious aggregation and loss of catalytic activity of the new nanocatalyst were observed after 10 runs in the reaction.
关键词[WOS]: ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ;  ULTRAFINE PALLADIUM NANOPARTICLES ;  SUPPORTED GOLD CATALYSTS ;  SELECTIVE HYDROGENATION ;  ROOM-TEMPERATURE ;  NITRO-COMPOUNDS ;  FUNCTIONALIZED NITROARENES ;  HIGHLY EFFICIENT ;  REDUCTION ;  OXIDE
语种: 英语
WOS记录号: WOS:000404514500017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152123
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Collaborat Innovat Ctr Chem Energy Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Ding, Zong-Cang,Li, Cun-Yao,Chen, Jun-Jia,et al. Palladium/Phosphorus-Doped Porous Organic Polymer as Recyclable Chemoselective and Efficient Hydrogenation Catalyst under Ambient Conditions[J]. ADVANCED SYNTHESIS & CATALYSIS,2017,359:2280-2287.
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