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Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides
Li, Xiaofang1,2; Jia, Xiuquan1; Ma, Jiping1; Xu, Yongming1,2; Huang, Yizheng1; Xu, Jie1
KeywordCatalysis Alkali Manganese Oxides 5-hydroxymethylfurfural Ammoxidation 2 5-furandicarboxamide
Source PublicationCHINESE JOURNAL OF CHEMISTRY
2017-06-01
DOI10.1002/cjoc.201600801
Volume35Pages:984-990
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordEFFICIENT AEROBIC OXIDATION ; SELECTIVE OXIDATION ; MILD CONDITIONS ; 2,5-DIFORMYLFURAN ; ALCOHOLS ; BIOMASS ; AMINES ; CONVERSION ; CHEMICALS ; AMIDES
Abstract2,5-Furandicarboxamide was firstly synthesized in yield of 85% via catalytic oxidative amidation of 5-hydroxymethylfurfural with aqueous NH3 over alkali manganese oxides of alpha-MnO2/NaxMnO2. The intermediates of 5-hydroxymethyl-furonitrile, 2,5-dicyanofuran, and 5-cyano-2-furancarboxamide were verified and their reactivities were further examined. The kinetic analysis results showed that the transformation of intermediate product of 5-cyano-2-furancarboxamide to 2,5-furan-dicarboxamide is a slower step, which is closely relative to the reaction temperature and basicity of catalyst.
Language英语
WOS IDWOS:000404029500032
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152129
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Xiaofang,Jia, Xiuquan,Ma, Jiping,et al. Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35:984-990.
APA Li, Xiaofang,Jia, Xiuquan,Ma, Jiping,Xu, Yongming,Huang, Yizheng,&Xu, Jie.(2017).Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides.CHINESE JOURNAL OF CHEMISTRY,35,984-990.
MLA Li, Xiaofang,et al."Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides".CHINESE JOURNAL OF CHEMISTRY 35(2017):984-990.
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