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题名: Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides
作者: Li, Xiaofang1, 2;  Jia, Xiuquan1;  Ma, Jiping1;  Xu, Yongming1, 2;  Huang, Yizheng1;  Xu, Jie1
关键词: catalysis ;  alkali manganese oxides ;  5-hydroxymethylfurfural ;  ammoxidation ;  2,5-furandicarboxamide
刊名: CHINESE JOURNAL OF CHEMISTRY
发表日期: 2017-06-01
DOI: 10.1002/cjoc.201600801
卷: 35, 页:984-990
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: 2,5-Furandicarboxamide was firstly synthesized in yield of 85% via catalytic oxidative amidation of 5-hydroxymethylfurfural with aqueous NH3 over alkali manganese oxides of alpha-MnO2/NaxMnO2. The intermediates of 5-hydroxymethyl-furonitrile, 2,5-dicyanofuran, and 5-cyano-2-furancarboxamide were verified and their reactivities were further examined. The kinetic analysis results showed that the transformation of intermediate product of 5-cyano-2-furancarboxamide to 2,5-furan-dicarboxamide is a slower step, which is closely relative to the reaction temperature and basicity of catalyst.
关键词[WOS]: EFFICIENT AEROBIC OXIDATION ;  SELECTIVE OXIDATION ;  MILD CONDITIONS ;  2,5-DIFORMYLFURAN ;  ALCOHOLS ;  BIOMASS ;  AMINES ;  CONVERSION ;  CHEMICALS ;  AMIDES
语种: 英语
WOS记录号: WOS:000404029500032
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152129
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Li, Xiaofang,Jia, Xiuquan,Ma, Jiping,et al. Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35:984-990.
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