中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates
作者: Wang, Wenlong1;  Wang, Yuqing1, 3;  Li, Cunyao1;  Yan, Li1;  Jiang, Miao1;  Ding, Yunjie1, 2
关键词: Carbon dioxide ;  Polymeric catalyst ;  Heterogeneous catalyst ;  Cooperative catalysis ;  Cyclic carbonates
刊名: ACS SUSTAINABLE CHEMISTRY & ENGINEERING
发表日期: 2017-06-01
DOI: 10.1021/acssuschemeng.7b00947
卷: 5, 页:4523-4528
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A single-component multifunctional catalyst (denoted as Mg-por/pho@POP) based on a magnesium porphyrin and phosphonium salt-integrated porous organic polymer (POP) was afforded via a solvothermal synthetic technique for cyclic carbonate production which uses epoxides and CO2. In consequence of the cooperative (or synergistic) effect of a phosphonium salt and homogeneously dispersed magnesium porphyrin moiety, which is possibly reinforced through the flexible frameworks and confined microporous structure, this powerful catalyst offered the highest activity of a heterogeneous catalyst within the context of cyclic carbonates synthesis from epoxide and CO2 (turnover frequencies up to 15,600 h(-1)) without the addition of co-catalysts. More surprisingly, very promising turnover numbers (TONs) of 14,400 and 4200 were realized at very mild temperatures of 25 and 40 degrees C. Moreover, Mg-por/pho@POP can be simply recovered and reused at least five times.
关键词[WOS]: POROUS ORGANIC POLYMERS ;  CONJUGATED MICROPOROUS POLYMER ;  HIGHLY EFFICIENT CATALYSTS ;  DIOXIDE UTILIZATION ;  AMBIENT CONDITIONS ;  PHOSPHONIUM SALT ;  EPOXIDES ;  CAPTURE ;  CONVERSION ;  COMPLEXES
语种: 英语
WOS记录号: WOS:000402950000007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152184
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China

Recommended Citation:
Wang, Wenlong,Wang, Yuqing,Li, Cunyao,et al. State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5:4523-4528.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Wang, Wenlong]'s Articles
 [Wang, Yuqing]'s Articles
 [Li, Cunyao]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Wang, Wenlong]‘s Articles
 [Wang, Yuqing]‘s Articles
 [Li, Cunyao]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace