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State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates
Wang, Wenlong1; Wang, Yuqing1,3; Li, Cunyao1; Yan, Li1; Jiang, Miao1; Ding, Yunjie1,2
关键词Carbon Dioxide Polymeric Catalyst Heterogeneous Catalyst Cooperative Catalysis Cyclic Carbonates
刊名ACS SUSTAINABLE CHEMISTRY & ENGINEERING
2017-06-01
DOI10.1021/acssuschemeng.7b00947
5页:4523-4528
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Multidisciplinary ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]POROUS ORGANIC POLYMERS ; CONJUGATED MICROPOROUS POLYMER ; HIGHLY EFFICIENT CATALYSTS ; DIOXIDE UTILIZATION ; AMBIENT CONDITIONS ; PHOSPHONIUM SALT ; EPOXIDES ; CAPTURE ; CONVERSION ; COMPLEXES
英文摘要A single-component multifunctional catalyst (denoted as Mg-por/pho@POP) based on a magnesium porphyrin and phosphonium salt-integrated porous organic polymer (POP) was afforded via a solvothermal synthetic technique for cyclic carbonate production which uses epoxides and CO2. In consequence of the cooperative (or synergistic) effect of a phosphonium salt and homogeneously dispersed magnesium porphyrin moiety, which is possibly reinforced through the flexible frameworks and confined microporous structure, this powerful catalyst offered the highest activity of a heterogeneous catalyst within the context of cyclic carbonates synthesis from epoxide and CO2 (turnover frequencies up to 15,600 h(-1)) without the addition of co-catalysts. More surprisingly, very promising turnover numbers (TONs) of 14,400 and 4200 were realized at very mild temperatures of 25 and 40 degrees C. Moreover, Mg-por/pho@POP can be simply recovered and reused at least five times.
语种英语
WOS记录号WOS:000402950000007
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152184
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China
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Wang, Wenlong,Wang, Yuqing,Li, Cunyao,et al. State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2017,5:4523-4528.
APA Wang, Wenlong,Wang, Yuqing,Li, Cunyao,Yan, Li,Jiang, Miao,&Ding, Yunjie.(2017).State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,5,4523-4528.
MLA Wang, Wenlong,et al."State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 5(2017):4523-4528.
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