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Y-Doped Na3V2(PO4)(2)F-3 compounds for sodium ion battery cathodes: electrochemical performance and analysis of kinetic properties
Liu, Wanqiu1; Yi, Hongming1,2; Zheng, Qiong1; Li, Xianfeng1,3; Zhang, Huamin1,3
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
2017-06-14
DOI10.1039/c7ta03133e
Volume5Pages:10928-10935
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS KeywordLITHIUM-ION ; ELECTRODE MATERIAL ; HIGH-POWER ; CAPABILITY ; CHALLENGES ; COMPOSITE ; GRAPHENE ; CELL
AbstractTo improve the intrinsic electronic conductivity and Na ion mobility of Na3V2(PO4)(2)F-3 (NVPF), Y(yttrium) atoms are introduced into the NVPF/C complex as a partial substitute for V(vanadium) through a sol-gel method. The effects of Y substitution on the crystal structure, morphology, electrochemical performance and kinetic properties of NVPF were investigated. Based on the battery performance comparison of the Na3V2-xYx(PO4)(3)/C (x = 0, 0.05, 0.1 and 0.2) samples, Na3V1.9Y0.1(PO4)(3)/C showed the best electrochemical performance and cycling stability. At a low rate of 0.5C, the 5 mol% Y-doped sample delivered a discharge capacity of 121.3 mA h g(-1), which was very close to the theoretical specific capacity. And even at a high rate of 50C, the discharge capacity achieved was higher than 80 mA h g(-1). After 200 cycles, the capacity retention of Na3V1.9Y0.1(PO4)(3)/C could still remain as high as 93.46% at 1C. From the morphology determination and analysis of kinetic properties, it was confirmed that the excellent electrochemical performance of Na3V1.9Y0.1(PO4)(3)/C was mainly due to the enhanced intrinsic electronic conductivity and Na ion mobility caused by introducing a moderate amount of Y to replace the V sites in the NVPF crystal structure. In order to get a better understanding of the relationship between the kinetic properties and the electrochemical performance in a sodium ion battery, a mass and electron transfer process model has been proposed for the first time in the present research.
Language英语
WOS IDWOS:000402734600018
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152191
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Wanqiu,Yi, Hongming,Zheng, Qiong,et al. Y-Doped Na3V2(PO4)(2)F-3 compounds for sodium ion battery cathodes: electrochemical performance and analysis of kinetic properties[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5:10928-10935.
APA Liu, Wanqiu,Yi, Hongming,Zheng, Qiong,Li, Xianfeng,&Zhang, Huamin.(2017).Y-Doped Na3V2(PO4)(2)F-3 compounds for sodium ion battery cathodes: electrochemical performance and analysis of kinetic properties.JOURNAL OF MATERIALS CHEMISTRY A,5,10928-10935.
MLA Liu, Wanqiu,et al."Y-Doped Na3V2(PO4)(2)F-3 compounds for sodium ion battery cathodes: electrochemical performance and analysis of kinetic properties".JOURNAL OF MATERIALS CHEMISTRY A 5(2017):10928-10935.
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