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Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide
Ni, Xiao-Lei1; Liu, Jing1; Liu, Ying-Ya1; Leus, Karen2; Depauw, Hannes2; Wang, An-Jie1,3; Van Der Voort, Pascal2; Zhang, Jian1,4; Hu, Yong-Kang1,3
KeywordMetal-organic Framework Molybdenum Cumene Hydroperoxide Propylene Epoxidation
Source PublicationCHINESE CHEMICAL LETTERS
2017-05-01
DOI10.1016/j.cclet.2017.01.020
Volume28Pages:1057-1061
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordOLEFINS ; COMPLEXES ; MOO3/SIO2 ; OXIDATION ; PROPENE ; ACID
AbstractTwo types of Mo containing metal-organic frameworks, denoted as Mo@COMOC-4 and PMA@MIL-101 (Cr), were synthesized respectively by a post-synthetic modification and a ship-in-bottle approach. The catalytic performance of both compounds in the epoxidation of propylene using cumene hydroperoxide (CHP) as oxidant was compared with MoO3@SiO2. A higher conversion (46.2%) and efficiency (87.4%) of CHP was observed for Mo@COMOC-4, whereas the heteropoly acids supported MIL-101 resulted in the decomposition of CHP due to its strong acidic character. Regenerability tests demonstrated that Mo@COMOC-4 could be reused for multiple runs without significant loss in both activity and stability. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000402444600026
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152223
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
2.Univ Ghent, Dept Inorgan & Phys Chem, COMOC, Krijgslaan 281-S3, B-9000 Ghent, Belgium
3.Liaoning Key Lab Petrochem Technol & Equipments, Dalian 116024, Peoples R China
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Ni, Xiao-Lei,Liu, Jing,Liu, Ying-Ya,et al. Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide[J]. CHINESE CHEMICAL LETTERS,2017,28:1057-1061.
APA Ni, Xiao-Lei.,Liu, Jing.,Liu, Ying-Ya.,Leus, Karen.,Depauw, Hannes.,...&Hu, Yong-Kang.(2017).Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide.CHINESE CHEMICAL LETTERS,28,1057-1061.
MLA Ni, Xiao-Lei,et al."Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide".CHINESE CHEMICAL LETTERS 28(2017):1057-1061.
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