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Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide
Ni, Xiao-Lei1; Liu, Jing1; Liu, Ying-Ya1; Leus, Karen2; Depauw, Hannes2; Wang, An-Jie1,3; Van Der Voort, Pascal2; Zhang, Jian1,4; Hu, Yong-Kang1,3
关键词Metal-organic Framework Molybdenum Cumene Hydroperoxide Propylene Epoxidation
刊名CHINESE CHEMICAL LETTERS
2017-05-01
DOI10.1016/j.cclet.2017.01.020
28页:1057-1061
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]OLEFINS ; COMPLEXES ; MOO3/SIO2 ; OXIDATION ; PROPENE ; ACID
英文摘要Two types of Mo containing metal-organic frameworks, denoted as Mo@COMOC-4 and PMA@MIL-101 (Cr), were synthesized respectively by a post-synthetic modification and a ship-in-bottle approach. The catalytic performance of both compounds in the epoxidation of propylene using cumene hydroperoxide (CHP) as oxidant was compared with MoO3@SiO2. A higher conversion (46.2%) and efficiency (87.4%) of CHP was observed for Mo@COMOC-4, whereas the heteropoly acids supported MIL-101 resulted in the decomposition of CHP due to its strong acidic character. Regenerability tests demonstrated that Mo@COMOC-4 could be reused for multiple runs without significant loss in both activity and stability. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000402444600026
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152223
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
2.Univ Ghent, Dept Inorgan & Phys Chem, COMOC, Krijgslaan 281-S3, B-9000 Ghent, Belgium
3.Liaoning Key Lab Petrochem Technol & Equipments, Dalian 116024, Peoples R China
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Ni, Xiao-Lei,Liu, Jing,Liu, Ying-Ya,et al. Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide[J]. CHINESE CHEMICAL LETTERS,2017,28:1057-1061.
APA Ni, Xiao-Lei.,Liu, Jing.,Liu, Ying-Ya.,Leus, Karen.,Depauw, Hannes.,...&Hu, Yong-Kang.(2017).Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide.CHINESE CHEMICAL LETTERS,28,1057-1061.
MLA Ni, Xiao-Lei,et al."Synthesis, characterization and catalytic performance of Mo based metal- organic frameworks in the epoxidation of propylene by cumene hydroperoxide".CHINESE CHEMICAL LETTERS 28(2017):1057-1061.
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