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Fe(III) doped NiS2 nanosheet: a highly efficient and low-cost hydrogen evolution catalyst
Yan, Junqing1; Wu, Huan1; Li, Ping1; Chen, Hong1; Jiang, Ruibin1; Liu, Shengzhong (Frank)1,2
刊名JOURNAL OF MATERIALS CHEMISTRY A
2017-06-07
DOI10.1039/c6ta11041j
5页:10173-10181
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Energy & Fuels ; Materials Science
关键词[WOS]MOS2 NANOPARTICLES ; BASIC SOLUTIONS ; WATER ; ELECTROCATALYST ; PHOTOCATALYST ; GENERATION ; NANOWIRE ; CDS ; CATHODE ; FOAM
英文摘要Sustainable hydrogen generation via electrocatalytic/photocatalytic water splitting has been widely regarded as the most promising energy carrier and has attracted extensive attention. However, a considerable hydrogen evolution reaction (HER) always involves the rare noble metals. Herein, we report a new HER candidate, an Fe-doped NiS2 (Fe-NiS2) nanosheet, with the performance of high activity and electrochemical stability. We chose the sulfidation of Ni(OH)(2) under mild calcinated temperature for Fe-NiS2 formation. The theoretical and experimental results suggest that the Fe3+ doping into the surface lattice of the NiS2 (002) facet lowers the activation energy of H-2 generation. The synthesized Fe-NiS2 sample shows good electrocatalytic HER performance with a low Tafel slope of 37 mV dec(-1) and a small overpotential of 121 mV at 10 mA cm(-2). Moreover, Fe-NiS2 gives considerable stability with a negligible loss of HER value l after a reaction of 1100 min. The Fe-NiS2 sample is also in situ loaded onto the surface of CdS nanorods to act as a co-catalyst for photocatalytic H-2 generation with the result of 3.2 mmol h(-1) g(-1) hydrogen evolution under visible light, 46 times higher than with bare CdS. This work can help us to design new electrocatalysts for water splitting; it also provides a good understanding of the hydrogen evolution pathway.
语种英语
WOS记录号WOS:000402387900009
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152228
专题中国科学院大连化学物理研究所
作者单位1.Shaanxi Normal Univ, Sch Mat Sci & Engn, Shaanxi Engn Lab Adv Energy Technol, Key Lab Appl Surface & Colloid Chem,Natl Minist E, Xian 710119, Peoples R China
2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, iChEM, Dalian 116023, Peoples R China
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Yan, Junqing,Wu, Huan,Li, Ping,et al. Fe(III) doped NiS2 nanosheet: a highly efficient and low-cost hydrogen evolution catalyst[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5:10173-10181.
APA Yan, Junqing,Wu, Huan,Li, Ping,Chen, Hong,Jiang, Ruibin,&Liu, Shengzhong .(2017).Fe(III) doped NiS2 nanosheet: a highly efficient and low-cost hydrogen evolution catalyst.JOURNAL OF MATERIALS CHEMISTRY A,5,10173-10181.
MLA Yan, Junqing,et al."Fe(III) doped NiS2 nanosheet: a highly efficient and low-cost hydrogen evolution catalyst".JOURNAL OF MATERIALS CHEMISTRY A 5(2017):10173-10181.
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